Formation of silver nanoparticles under structured amino groups in pseudo-dendritic poly(allylamine) derivatives

Ping Lin Kuo; Wei Fu Chen

doi:10.1021/jp030116s

Formation of silver nanoparticles under structured amino groups in pseudo-dendritic poly(allylamine) derivatives

Ping Lin Kuo, Wei Fu Chen

Fire Protection and Safety Research Center

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

The syntheses of silver nanoparticles stabilized by poly(allylamine) (PAA) and by polyethyleneiminated poly(allylamine) (PAA(EI)_n (n = 2, 5.8)) are reported. The architectural effects in particle on the nanoparticle size, size distribution, and agglomeration behavior are determined from the UV-vis plasmon absorption band and transmission electron microscopic (TEM) analyses. The data show that PAA(EI)_n display better stabilizing effects than PAA to prevent silver particles from agglomeration. Different phenomena of the polymer-protected nanoparticles at various silver ion concentrations are observed and are explained in terms of a mechanism of structure-dependent stabilization.

Original language	English
Pages (from-to)	11267-11272
Number of pages	6
Journal	Journal of Physical Chemistry B
Volume	107
Issue number	41
DOIs	https://doi.org/10.1021/jp030116s
Publication status	Published - 2003 Oct 16

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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abstract = "The syntheses of silver nanoparticles stabilized by poly(allylamine) (PAA) and by polyethyleneiminated poly(allylamine) (PAA(EI)n (n = 2, 5.8)) are reported. The architectural effects in particle on the nanoparticle size, size distribution, and agglomeration behavior are determined from the UV-vis plasmon absorption band and transmission electron microscopic (TEM) analyses. The data show that PAA(EI)n display better stabilizing effects than PAA to prevent silver particles from agglomeration. Different phenomena of the polymer-protected nanoparticles at various silver ion concentrations are observed and are explained in terms of a mechanism of structure-dependent stabilization.",

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N2 - The syntheses of silver nanoparticles stabilized by poly(allylamine) (PAA) and by polyethyleneiminated poly(allylamine) (PAA(EI)n (n = 2, 5.8)) are reported. The architectural effects in particle on the nanoparticle size, size distribution, and agglomeration behavior are determined from the UV-vis plasmon absorption band and transmission electron microscopic (TEM) analyses. The data show that PAA(EI)n display better stabilizing effects than PAA to prevent silver particles from agglomeration. Different phenomena of the polymer-protected nanoparticles at various silver ion concentrations are observed and are explained in terms of a mechanism of structure-dependent stabilization.

AB - The syntheses of silver nanoparticles stabilized by poly(allylamine) (PAA) and by polyethyleneiminated poly(allylamine) (PAA(EI)n (n = 2, 5.8)) are reported. The architectural effects in particle on the nanoparticle size, size distribution, and agglomeration behavior are determined from the UV-vis plasmon absorption band and transmission electron microscopic (TEM) analyses. The data show that PAA(EI)n display better stabilizing effects than PAA to prevent silver particles from agglomeration. Different phenomena of the polymer-protected nanoparticles at various silver ion concentrations are observed and are explained in terms of a mechanism of structure-dependent stabilization.

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Formation of silver nanoparticles under structured amino groups in pseudo-dendritic poly(allylamine) derivatives

Abstract

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