TY - JOUR
T1 - Gasification kinetics of raw and wet-torrefied microalgae Chlorella vulgaris ESP-31 in carbon dioxide
AU - Bach, Quang Vu
AU - Chen, Wei Hsin
AU - Sheen, Herng Kuang
AU - Chang, Jo Shu
N1 - Funding Information:
The authors acknowledge the financial support from the Ministry of Science and Technology, Taiwan, R.O.C., under the contracts MOST 105-2811-E-006-003 and MOST 106-2923-E-006-002-MY3 for this research.
PY - 2017
Y1 - 2017
N2 - This study aims at investigating the gasification behavior and kinetics of microalga Chlorella vulgaris ESP-31 before and after wet torrefaction. The raw and wet-torrefied microalgae were first gasified in a thermogravimetric analyzer under a continuous CO2 flow. Thereafter, the obtained thermogravimetric data were modeled for kinetic study, employing a seven-parallel-reaction mechanism. The decomposition of the microalgae in CO2 shows two reactive stages: devolatilization with two peaks and gasification with a peak accompanied by a shoulder, and the thermal decomposition of components in the samples can be clearly identified. Increasing wet torrefaction temperature lowers the height of the major devolatilization peak but enhances the height of the minor one. Moreover, the kinetic evaluation reveals that wet torrefaction affects most of the kinetic parameters of the microalgal components. Furthermore, wet torrefaction temperature influences the kinetic parameters of carbohydrate and lipid, but not on those of protein, “others”, and chars.
AB - This study aims at investigating the gasification behavior and kinetics of microalga Chlorella vulgaris ESP-31 before and after wet torrefaction. The raw and wet-torrefied microalgae were first gasified in a thermogravimetric analyzer under a continuous CO2 flow. Thereafter, the obtained thermogravimetric data were modeled for kinetic study, employing a seven-parallel-reaction mechanism. The decomposition of the microalgae in CO2 shows two reactive stages: devolatilization with two peaks and gasification with a peak accompanied by a shoulder, and the thermal decomposition of components in the samples can be clearly identified. Increasing wet torrefaction temperature lowers the height of the major devolatilization peak but enhances the height of the minor one. Moreover, the kinetic evaluation reveals that wet torrefaction affects most of the kinetic parameters of the microalgal components. Furthermore, wet torrefaction temperature influences the kinetic parameters of carbohydrate and lipid, but not on those of protein, “others”, and chars.
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U2 - 10.1016/j.biortech.2017.03.153
DO - 10.1016/j.biortech.2017.03.153
M3 - Article
C2 - 28390786
AN - SCOPUS:85017134355
VL - 244
SP - 1393
EP - 1399
JO - Bioresource Technology
JF - Bioresource Technology
SN - 0960-8524
ER -