Gel electrolytes based on an ether-abundant polymeric framework for high-rate and long-cycle-life lithium ion batteries

Li Yu Huang, You Chao Shih, Shih Hong Wang, Ping-Lin Kuo, Hsisheng Teng

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

This study reports a gel polymer electrolyte (GPE) that is synthesized using a poly(ethylene oxide)-co-poly(propylene oxide) copolymer blending diglycidyl ether of bisphenol-A (i.e., P(EO-co-PO)) as a host swelled by a liquid electrolyte (LE) of 1 M LiPF6 in carbonate solvents. The P(EO-co-PO) copolymer in the GPE contains a high concentration of ether groups to coordinate solvent molecules and solvated Li+ ions for achieving high ionic conductivity (3.8 × 10-3 S cm-1 at 30 °C), and exhibits an excellent Li+ transference number of 0.7. The GPE is assembled in a full-cell lithium ion battery (LIB) consisting of an LiFePO4 cathode and a graphite anode, and the copolymer network facilitates ion motion to reduce the equivalent series resistance by 50% and increase the specific power by two times relative to the performance of an LIB assembled using the LE. This GPE-based LIB exhibits a capacity of 125 mA h g-1 at 0.1 C and is able to deliver 22 mA h g-1 of electricity at 15 C. This LIB exhibits superior stability; it presents negligible capacity decay after 200 charge-discharge cycles at 1 C and exhibits 77% capacity retention after 450 cycles. The distinctive merit of the GPE film is its mechanical integrity, which ensures that the roll-to-roll assembly of GPE-based LIBs is readily scalable to industrial levels.

Original languageEnglish
Pages (from-to)10492-10501
Number of pages10
JournalJournal of Materials Chemistry A
Volume2
Issue number27
DOIs
Publication statusPublished - 2014 Jul 21

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Ether
Electrolytes
Life cycle
Ethers
Gels
Polymers
UCON 50-HB-5100
Copolymers
Ions
Polypropylene oxides
Graphite
Lithium-ion batteries
Carbonates
Liquids
Ionic conductivity
Polyethylene oxides
Anodes
Cathodes
Electricity
Molecules

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

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title = "Gel electrolytes based on an ether-abundant polymeric framework for high-rate and long-cycle-life lithium ion batteries",
abstract = "This study reports a gel polymer electrolyte (GPE) that is synthesized using a poly(ethylene oxide)-co-poly(propylene oxide) copolymer blending diglycidyl ether of bisphenol-A (i.e., P(EO-co-PO)) as a host swelled by a liquid electrolyte (LE) of 1 M LiPF6 in carbonate solvents. The P(EO-co-PO) copolymer in the GPE contains a high concentration of ether groups to coordinate solvent molecules and solvated Li+ ions for achieving high ionic conductivity (3.8 × 10-3 S cm-1 at 30 °C), and exhibits an excellent Li+ transference number of 0.7. The GPE is assembled in a full-cell lithium ion battery (LIB) consisting of an LiFePO4 cathode and a graphite anode, and the copolymer network facilitates ion motion to reduce the equivalent series resistance by 50{\%} and increase the specific power by two times relative to the performance of an LIB assembled using the LE. This GPE-based LIB exhibits a capacity of 125 mA h g-1 at 0.1 C and is able to deliver 22 mA h g-1 of electricity at 15 C. This LIB exhibits superior stability; it presents negligible capacity decay after 200 charge-discharge cycles at 1 C and exhibits 77{\%} capacity retention after 450 cycles. The distinctive merit of the GPE film is its mechanical integrity, which ensures that the roll-to-roll assembly of GPE-based LIBs is readily scalable to industrial levels.",
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Gel electrolytes based on an ether-abundant polymeric framework for high-rate and long-cycle-life lithium ion batteries. / Huang, Li Yu; Shih, You Chao; Wang, Shih Hong; Kuo, Ping-Lin; Teng, Hsisheng.

In: Journal of Materials Chemistry A, Vol. 2, No. 27, 21.07.2014, p. 10492-10501.

Research output: Contribution to journalArticle

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