Gold-Catalyzed Addition of β-Oxo Enols at Tethered Alkynes via a Non-Conia-ene Pathway: Observation of a Formal 1,3-Hydroxymethylidene Migration

Chemistry

• Alkyne 100%
• Enol 100%
• Conia-Ene Reaction 100%
• formation 50%
• Carbene 50%
• Aldehyde 50%
• One Pot Reaction 50%
• Density Functional Theory 50%
• Indene 50%
• Cyclopropane 50%

Keyphrases

• Indanone Derivatives 50%
• Diazoester 50%
• 5-endo-dig 50%
• 2-Alkynylbenzaldehyde 50%
• Enolizable Aldehydes 50%