Hard X-ray photoemission study of Mn 2p core-levels of La 1-xSrxMnO3 thin films

K. Horiba; M. Taguchi; N. Kamakura; K. Yamamoto; A. Chainani; Y. Takata; E. Ikenaga; H. Namatame; M. Taniguchi; M. Awaji; A. Takeuchi; D. Miwa; Y. Nishino; K. Tamasaku; T. Ishikawa; H. Kumigashira; M. Oshima; M. Lippmaa; M. Kawasaki; H. Koinuma; K. Kobayashi; S. Shin

doi:10.1016/j.elspec.2005.01.008

Hard X-ray photoemission study of Mn 2p core-levels of La _1-xSr_xMnO₃ thin films

K. Horiba, M. Taguchi, N. Kamakura, K. Yamamoto, A. Chainani, Y. Takata, E. Ikenaga, H. Namatame, M. Taniguchi, M. Awaji, A. Takeuchi, D. Miwa, Y. Nishino, K. Tamasaku, T. Ishikawa, H. Kumigashira, M. Oshima, M. Lippmaa, M. Kawasaki, H. KoinumaK. Kobayashi, S. Shin

Department of Physics

Research output: Contribution to journal › Article › peer-review

Abstract

In order to clarify the intrinsic bulk electronic structure of La _1-xSr_xMnO₃ (LSMO) thin films, we have performed high-energy (hν=5.95 keV) synchrotron photoemission spectroscopy (PES) of Mn 2p core-levels. In sharp contrast with the previous soft X-ray PES (hν=800-1486.6 eV), the high-energy PES spectra exhibit a clear additional peak at the low binding-energy side of the Mn 2p_3/2 peak. To check for surface sensitivity, we measured take-off-angle dependence of Mn 2p core-levels. The results indicate that this additional peak originates from the bulk electronic structure. The peak shows a noticeable increase in the metallic phase of LSMO for x=0.2 and 0.4, indicating that the origin of this peak is strongly related to the metallic physical properties of LSMO thin films. A single ion (MO6) cluster calculation including charge transfer from doping-induced states reproduces the new bulk-derived feature observed in Mn 2p core-levels.

Original language	English
Pages (from-to)	557-559
Number of pages	3
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	144-147
DOIs	https://doi.org/10.1016/j.elspec.2005.01.008
Publication status	Published - 2005 Jun

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

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10.1016/j.elspec.2005.01.008

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Horiba, K., Taguchi, M., Kamakura, N., Yamamoto, K., Chainani, A., Takata, Y., Ikenaga, E., Namatame, H., Taniguchi, M., Awaji, M., Takeuchi, A., Miwa, D., Nishino, Y., Tamasaku, K., Ishikawa, T., Kumigashira, H., Oshima, M., Lippmaa, M., Kawasaki, M., ... Shin, S. (2005). Hard X-ray photoemission study of Mn 2p core-levels of La _1-xSr_xMnO₃ thin films. Journal of Electron Spectroscopy and Related Phenomena, 144-147, 557-559. https://doi.org/10.1016/j.elspec.2005.01.008

@article{0b1e85390404433d91ecee96d1677709,

title = "Hard X-ray photoemission study of Mn 2p core-levels of La 1-xSrxMnO3 thin films",

abstract = "In order to clarify the intrinsic bulk electronic structure of La 1-xSrxMnO3 (LSMO) thin films, we have performed high-energy (hν=5.95 keV) synchrotron photoemission spectroscopy (PES) of Mn 2p core-levels. In sharp contrast with the previous soft X-ray PES (hν=800-1486.6 eV), the high-energy PES spectra exhibit a clear additional peak at the low binding-energy side of the Mn 2p3/2 peak. To check for surface sensitivity, we measured take-off-angle dependence of Mn 2p core-levels. The results indicate that this additional peak originates from the bulk electronic structure. The peak shows a noticeable increase in the metallic phase of LSMO for x=0.2 and 0.4, indicating that the origin of this peak is strongly related to the metallic physical properties of LSMO thin films. A single ion (MO6) cluster calculation including charge transfer from doping-induced states reproduces the new bulk-derived feature observed in Mn 2p core-levels.",

author = "K. Horiba and M. Taguchi and N. Kamakura and K. Yamamoto and A. Chainani and Y. Takata and E. Ikenaga and H. Namatame and M. Taniguchi and M. Awaji and A. Takeuchi and D. Miwa and Y. Nishino and K. Tamasaku and T. Ishikawa and H. Kumigashira and M. Oshima and M. Lippmaa and M. Kawasaki and H. Koinuma and K. Kobayashi and S. Shin",

year = "2005",

month = jun,

doi = "10.1016/j.elspec.2005.01.008",

language = "English",

volume = "144-147",

pages = "557--559",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

}

Horiba, K, Taguchi, M, Kamakura, N, Yamamoto, K, Chainani, A, Takata, Y, Ikenaga, E, Namatame, H, Taniguchi, M, Awaji, M, Takeuchi, A, Miwa, D, Nishino, Y, Tamasaku, K, Ishikawa, T, Kumigashira, H, Oshima, M, Lippmaa, M, Kawasaki, M, Koinuma, H, Kobayashi, K & Shin, S 2005, 'Hard X-ray photoemission study of Mn 2p core-levels of La _1-xSr_xMnO₃ thin films', Journal of Electron Spectroscopy and Related Phenomena, vol. 144-147, pp. 557-559. https://doi.org/10.1016/j.elspec.2005.01.008

TY - JOUR

T1 - Hard X-ray photoemission study of Mn 2p core-levels of La 1-xSrxMnO3 thin films

AU - Horiba, K.

AU - Taguchi, M.

AU - Kamakura, N.

AU - Yamamoto, K.

AU - Chainani, A.

AU - Takata, Y.

AU - Ikenaga, E.

AU - Namatame, H.

AU - Taniguchi, M.

AU - Awaji, M.

AU - Takeuchi, A.

AU - Miwa, D.

AU - Nishino, Y.

AU - Tamasaku, K.

AU - Ishikawa, T.

AU - Kumigashira, H.

AU - Oshima, M.

AU - Lippmaa, M.

AU - Kawasaki, M.

AU - Koinuma, H.

AU - Kobayashi, K.

AU - Shin, S.

PY - 2005/6

Y1 - 2005/6

N2 - In order to clarify the intrinsic bulk electronic structure of La 1-xSrxMnO3 (LSMO) thin films, we have performed high-energy (hν=5.95 keV) synchrotron photoemission spectroscopy (PES) of Mn 2p core-levels. In sharp contrast with the previous soft X-ray PES (hν=800-1486.6 eV), the high-energy PES spectra exhibit a clear additional peak at the low binding-energy side of the Mn 2p3/2 peak. To check for surface sensitivity, we measured take-off-angle dependence of Mn 2p core-levels. The results indicate that this additional peak originates from the bulk electronic structure. The peak shows a noticeable increase in the metallic phase of LSMO for x=0.2 and 0.4, indicating that the origin of this peak is strongly related to the metallic physical properties of LSMO thin films. A single ion (MO6) cluster calculation including charge transfer from doping-induced states reproduces the new bulk-derived feature observed in Mn 2p core-levels.

AB - In order to clarify the intrinsic bulk electronic structure of La 1-xSrxMnO3 (LSMO) thin films, we have performed high-energy (hν=5.95 keV) synchrotron photoemission spectroscopy (PES) of Mn 2p core-levels. In sharp contrast with the previous soft X-ray PES (hν=800-1486.6 eV), the high-energy PES spectra exhibit a clear additional peak at the low binding-energy side of the Mn 2p3/2 peak. To check for surface sensitivity, we measured take-off-angle dependence of Mn 2p core-levels. The results indicate that this additional peak originates from the bulk electronic structure. The peak shows a noticeable increase in the metallic phase of LSMO for x=0.2 and 0.4, indicating that the origin of this peak is strongly related to the metallic physical properties of LSMO thin films. A single ion (MO6) cluster calculation including charge transfer from doping-induced states reproduces the new bulk-derived feature observed in Mn 2p core-levels.

UR - http://www.scopus.com/inward/record.url?scp=20244372723&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=20244372723&partnerID=8YFLogxK

U2 - 10.1016/j.elspec.2005.01.008

DO - 10.1016/j.elspec.2005.01.008

M3 - Article

AN - SCOPUS:20244372723

SN - 0368-2048

VL - 144-147

SP - 557

EP - 559

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

ER -

Hard X-ray photoemission study of Mn 2p core-levels of La _1-xSr_xMnO₃ thin films

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