Hierarchically structured superhydrophobic coatings fabricated by successive Langmuir-Blodgett deposition of micro-/nano-sized particles and surface silanization

Ping Szu Tsai, Yu Min Yang, Yuh-Lang Lee

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52 Citations (Scopus)

Abstract

The present study demonstrates the creation of a stable, superhydrophobic surface by coupling of successive Langmuir-Blodgett (LB) depositions of micro- and nano-sized (1.5 μm/50 nm, 1.0 μm/50 nm, and 0.5 μm/50 nm) silica particles on a glass substrate with the formation of a self-assembled monolayer of dodecyltrichlorosilane on the surface of the particulate film. Particulate films, in which one layer of 50 nm particles was deposited over one to five sublayers of larger micro-sized particles, with hierarchical surface roughness and superhydrophobicity, were successfully fabricated. Furthermore, the present 'two-scale' (micro- and nano-sized particles) approach is superior to the previous 'one-scale' (micro-sized particles) approach in that both higher advancing contact angle and lower contact angle hysteresis can be realized. Experimental results revealed that the superhydrophobicity exhibited by as-fabricated particulate films with different sublayer particle diameters increases in the order of 0.5 μm>1.0 μm>1.5 μm. However, no clear trend between sublayer number and surface superhydrophobicity could be discerned. An explanation of superhydrophobicity based on the surface roughness introduced by two-scale particles is also proposed.

Original languageEnglish
Article number465604
JournalNanotechnology
Volume18
Issue number46
DOIs
Publication statusPublished - 2007 Nov 21

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

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