TY - JOUR
T1 - High nuclearity molecular species exhibiting spin frustration
T2 - Fusion of two MnIII4O2 butterfly complexes to yield an intermediate spin ground state MnIII7O4 complex
AU - Wang, Sheyi
AU - Tsai, Hui Lien
AU - Streib, William E.
AU - Christou, George
AU - Hendrickson, David N.
PY - 1992/12/1
Y1 - 1992/12/1
N2 - The preparation and characterization of (NEt4)[Mn 7O4(OAc)10(dbm)4]·3CH 2Cl2·2C6H14 (1·3CH2Cl2·2C6H14) (H dbm = dibenzoylmethane)are reported; the MnIII7O 4 core of 1 consists of two Mn4O2 butterfly units fused together by sharing of one wing-tip manganese atom and it is shown using magnetization data that complex 1 has either an S = 3 or S = 4 ground state.
AB - The preparation and characterization of (NEt4)[Mn 7O4(OAc)10(dbm)4]·3CH 2Cl2·2C6H14 (1·3CH2Cl2·2C6H14) (H dbm = dibenzoylmethane)are reported; the MnIII7O 4 core of 1 consists of two Mn4O2 butterfly units fused together by sharing of one wing-tip manganese atom and it is shown using magnetization data that complex 1 has either an S = 3 or S = 4 ground state.
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U2 - 10.1039/C39920000677
DO - 10.1039/C39920000677
M3 - Article
AN - SCOPUS:37049081263
SN - 0022-4936
SP - 677
EP - 679
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 9
ER -