High-Speed Lithium-Ion Transfer inside Mesoporous Core-Shell LiFePO4/Carbon-Sphere Cathodes

Chun Han Hsu, Hsin Yi Liao, Ping Lin Kuo

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A thin layer of LiFePO4 was coated onto a mesoporous carbon sphere to obtain a mesoporous core-shell LiFePO4/carbon sphere (LFP/MCS) composite, for which the thickness of the nanoscale LiFePO4 thin shell was approximately 30-50nm. Meanwhile, pristine LFP and MCS mixed with LFP samples (MCS-m-LFP) were prepared for comparison. The significantly larger surface area of LFP/MCS (43-151m2g-1) compared with pristine LFP (12m2g-1) is derived from the mesoporous carbon framework and thin nanoscale LFP shell. The large surface area of LFP/MCS provides greater surface content between the LiFePO4 shell and electrolytes, which results in a high charge-discharge rate. Also, this remarkably thin LiFePO4 cathode shell shortens the diffusion length of lithium ions thereby achieving a high charge-discharge rate for electrode materials. Consequently, under all charge-discharge rates (0.1-20C), the specific capacities of LFP/MCS are higher than those of both the pristine LFP and MCS-m-LFP. More specifically, at 10C, LFP/MCS exhibited the excellent rate performance of 82mAhg-1, compared to 25 and 41mAhg-1 for LFP and MCS-m-LFP, respectively. Furthermore, the discharge capacity for LFP/MCS at the high discharge rate of 20C remains stable whereas that for LFP does not. This demonstrates the efficient transport capability of Li ions into the nanoscale LFP shell in the core-shell structure of LFP/MCS, which is essential for the improvement of the electrochemical performance.

Original languageEnglish
Pages (from-to)409-413
Number of pages5
JournalEnergy Technology
Volume2
Issue number4
DOIs
Publication statusPublished - 2014 Apr 1

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Lithium
Cathodes
Carbon
Ions
Electrolytes
Electrodes
Composite materials

All Science Journal Classification (ASJC) codes

  • Energy(all)

Cite this

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title = "High-Speed Lithium-Ion Transfer inside Mesoporous Core-Shell LiFePO4/Carbon-Sphere Cathodes",
abstract = "A thin layer of LiFePO4 was coated onto a mesoporous carbon sphere to obtain a mesoporous core-shell LiFePO4/carbon sphere (LFP/MCS) composite, for which the thickness of the nanoscale LiFePO4 thin shell was approximately 30-50nm. Meanwhile, pristine LFP and MCS mixed with LFP samples (MCS-m-LFP) were prepared for comparison. The significantly larger surface area of LFP/MCS (43-151m2g-1) compared with pristine LFP (12m2g-1) is derived from the mesoporous carbon framework and thin nanoscale LFP shell. The large surface area of LFP/MCS provides greater surface content between the LiFePO4 shell and electrolytes, which results in a high charge-discharge rate. Also, this remarkably thin LiFePO4 cathode shell shortens the diffusion length of lithium ions thereby achieving a high charge-discharge rate for electrode materials. Consequently, under all charge-discharge rates (0.1-20C), the specific capacities of LFP/MCS are higher than those of both the pristine LFP and MCS-m-LFP. More specifically, at 10C, LFP/MCS exhibited the excellent rate performance of 82mAhg-1, compared to 25 and 41mAhg-1 for LFP and MCS-m-LFP, respectively. Furthermore, the discharge capacity for LFP/MCS at the high discharge rate of 20C remains stable whereas that for LFP does not. This demonstrates the efficient transport capability of Li ions into the nanoscale LFP shell in the core-shell structure of LFP/MCS, which is essential for the improvement of the electrochemical performance.",
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High-Speed Lithium-Ion Transfer inside Mesoporous Core-Shell LiFePO4/Carbon-Sphere Cathodes. / Hsu, Chun Han; Liao, Hsin Yi; Kuo, Ping Lin.

In: Energy Technology, Vol. 2, No. 4, 01.04.2014, p. 409-413.

Research output: Contribution to journalArticle

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