High spin molecules: A structural and magnetic comparison of high nuclearity manganese carboxylate aggregates

Hilary J. Eppley, Sheyi Wang, Hui Lien Tsai, Sheila M. Aubin, Kirsten Folting, William E. Streib, David N. Hendrickson, George Christou

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

A structural and magnetic comparison is presented for a number of high nuclearity, higher oxidation state manganese complexes with similar ligation environments. The complexes considered are hepta-, octa-, ennea-, deca-, and dodecanuclear and contain only Mnm, except for the dodecanuclear complexes, which are mixed valence (MnIIIgMnIV4). The ground state spins of these complexes range from very low to very high, and while the dodecanuclear complexes exhibit unusual AC magnetic susceptibility behavior, none of the other complexes show such properties. Magnetic properties, as well as structural and preparative information, are discussed.

Original languageEnglish
Pages (from-to)159-166
Number of pages8
JournalMolecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume274
Issue number1
DOIs
Publication statusPublished - 1995 Nov

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

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