TY - JOUR
T1 - High spin molecules
T2 - A structural and magnetic comparison of high nuclearity manganese carboxylate aggregates
AU - Eppley, Hilary J.
AU - Wang, Sheyi
AU - Tsai, Hui Lien
AU - Aubin, Sheila M.
AU - Folting, Kirsten
AU - Streib, William E.
AU - Hendrickson, David N.
AU - Christou, George
N1 - Funding Information:
This work is supported by NSF grants CHE-9115286 (D.N.H.) and CHE-8808019 and CHE-93 1 1904 (G.C.) The AC magnetic susceptibility measurements were performed with an AC SQUID susceptometer provided by the Center for Interface and Material Science, funded by the W. A. Keck Foundation. H.J.E. was supported by an NSF Predoctoral Fellowship.
PY - 1995/11
Y1 - 1995/11
N2 - A structural and magnetic comparison is presented for a number of high nuclearity, higher oxidation state manganese complexes with similar ligation environments. The complexes considered are hepta-, octa-, ennea-, deca-, and dodecanuclear and contain only Mnm, except for the dodecanuclear complexes, which are mixed valence (MnIIIgMnIV4). The ground state spins of these complexes range from very low to very high, and while the dodecanuclear complexes exhibit unusual AC magnetic susceptibility behavior, none of the other complexes show such properties. Magnetic properties, as well as structural and preparative information, are discussed.
AB - A structural and magnetic comparison is presented for a number of high nuclearity, higher oxidation state manganese complexes with similar ligation environments. The complexes considered are hepta-, octa-, ennea-, deca-, and dodecanuclear and contain only Mnm, except for the dodecanuclear complexes, which are mixed valence (MnIIIgMnIV4). The ground state spins of these complexes range from very low to very high, and while the dodecanuclear complexes exhibit unusual AC magnetic susceptibility behavior, none of the other complexes show such properties. Magnetic properties, as well as structural and preparative information, are discussed.
UR - https://www.scopus.com/pages/publications/0029516172
UR - https://www.scopus.com/pages/publications/0029516172#tab=citedBy
U2 - 10.1080/10587259508031876
DO - 10.1080/10587259508031876
M3 - Article
AN - SCOPUS:0029516172
SN - 1058-725X
VL - 274
SP - 159
EP - 166
JO - Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
IS - 1
ER -