High spin molecules

[Mn12O12(O2CCH2Cl)16(H2O)4] and the one-electron reduction product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]

Hui-Lien Tsai, Tyn Yih Jwo, Gene Hsiang Lee, Yu Wang

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reduced by PPh4I to give a reduced complex [PPh4][Mn12O12-(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexes were determined by the X-ray method. The dc magnetic susceptibility measurements indicate that the neutral and reduced complexes are high spin species.

Original languageEnglish
Pages (from-to)346-347
Number of pages2
JournalChemistry Letters
Issue number4
DOIs
Publication statusPublished - 2000 Jan 1

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Magnetic susceptibility
Crystal structure
X rays
Molecules
Electrons

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

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title = "High spin molecules: [Mn12O12(O2CCH2Cl)16(H2O)4] and the one-electron reduction product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]",
abstract = "The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reduced by PPh4I to give a reduced complex [PPh4][Mn12O12-(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexes were determined by the X-ray method. The dc magnetic susceptibility measurements indicate that the neutral and reduced complexes are high spin species.",
author = "Hui-Lien Tsai and Jwo, {Tyn Yih} and Lee, {Gene Hsiang} and Yu Wang",
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language = "English",
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journal = "Chemistry Letters",
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publisher = "Chemical Society of Japan",
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High spin molecules : [Mn12O12(O2CCH2Cl)16(H2O)4] and the one-electron reduction product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]. / Tsai, Hui-Lien; Jwo, Tyn Yih; Lee, Gene Hsiang; Wang, Yu.

In: Chemistry Letters, No. 4, 01.01.2000, p. 346-347.

Research output: Contribution to journalArticle

TY - JOUR

T1 - High spin molecules

T2 - [Mn12O12(O2CCH2Cl)16(H2O)4] and the one-electron reduction product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]

AU - Tsai, Hui-Lien

AU - Jwo, Tyn Yih

AU - Lee, Gene Hsiang

AU - Wang, Yu

PY - 2000/1/1

Y1 - 2000/1/1

N2 - The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reduced by PPh4I to give a reduced complex [PPh4][Mn12O12-(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexes were determined by the X-ray method. The dc magnetic susceptibility measurements indicate that the neutral and reduced complexes are high spin species.

AB - The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reduced by PPh4I to give a reduced complex [PPh4][Mn12O12-(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexes were determined by the X-ray method. The dc magnetic susceptibility measurements indicate that the neutral and reduced complexes are high spin species.

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U2 - 10.1246/cl.2000.346

DO - 10.1246/cl.2000.346

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

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