High spin molecules: [Mn12O12(O2CCH2Cl)16(H2O)4] and the one-electron reduction product [PPh4][Mn12O12(O2CCH2Cl)16(H2O)3]

Hui Lien Tsai, Tyn Yih Jwo, Gene Hsiang Lee, Yu Wang

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The complex of [Mn12O12(O2CCH2Cl)16(H2O)4] was reduced by PPh4I to give a reduced complex [PPh4][Mn12O12-(O2CCH2Cl)16(H2O)3]. Crystal structures of both complexes were determined by the X-ray method. The dc magnetic susceptibility measurements indicate that the neutral and reduced complexes are high spin species.

Original languageEnglish
Pages (from-to)346-347
Number of pages2
JournalChemistry Letters
Issue number4
DOIs
Publication statusPublished - 2000 Jan 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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