Abstract
Treatment of (NBun4)[Mn4O 2(O2CPh)9(H2O)] with Na 2(Et2mal) in MeCN leads to a nuclearity and oxidation level change to give (NBun4)2[Mn 8O4(O2CPh)12(Et2mal) 2(H2O)2] 1; the crystal structure and magnetochemical studies show the core of the anion to have a unique topology consisting of two linked [Mn4O2] butterfly units and to possess an S = 3 ground state, respectively.
Original language | English |
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Pages (from-to) | 1031-1034 |
Number of pages | 4 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 8 |
DOIs | |
Publication status | Published - 1994 Dec 1 |
All Science Journal Classification (ASJC) codes
- Molecular Medicine