Abstract
Treatment of (NBun4)[Mn4O 2(O2CPh)9(H2O)] with Na 2(Et2mal) in MeCN leads to a nuclearity and oxidation level change to give (NBun4)2[Mn 8O4(O2CPh)12(Et2mal) 2(H2O)2] 1; the crystal structure and magnetochemical studies show the core of the anion to have a unique topology consisting of two linked [Mn4O2] butterfly units and to possess an S = 3 ground state, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 1031-1034 |
| Number of pages | 4 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 1994 Dec 1 |
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All Science Journal Classification (ASJC) codes
- Molecular Medicine
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High spin molecules : (NBun4)2[Mn 8O4(O2CPh)12(Et2mal) 2(H2O)2], a mixed-valence managenese(II/III) aggregate with dicarboxylate ligation, an unusual linked-butterfly structure, and an S = 3 ground state. / Wemple, Michael W.; Tsai, Hui-Lien; Streib, William E.; Hendrickson, David N.; Christou, George.
In: Journal of the Chemical Society, Chemical Communications, No. 8, 01.12.1994, p. 1031-1034.Research output: Contribution to journal › Article
TY - JOUR
T1 - High spin molecules
T2 - (NBun4)2[Mn 8O4(O2CPh)12(Et2mal) 2(H2O)2], a mixed-valence managenese(II/III) aggregate with dicarboxylate ligation, an unusual linked-butterfly structure, and an S = 3 ground state
AU - Wemple, Michael W.
AU - Tsai, Hui-Lien
AU - Streib, William E.
AU - Hendrickson, David N.
AU - Christou, George
PY - 1994/12/1
Y1 - 1994/12/1
N2 - Treatment of (NBun4)[Mn4O 2(O2CPh)9(H2O)] with Na 2(Et2mal) in MeCN leads to a nuclearity and oxidation level change to give (NBun4)2[Mn 8O4(O2CPh)12(Et2mal) 2(H2O)2] 1; the crystal structure and magnetochemical studies show the core of the anion to have a unique topology consisting of two linked [Mn4O2] butterfly units and to possess an S = 3 ground state, respectively.
AB - Treatment of (NBun4)[Mn4O 2(O2CPh)9(H2O)] with Na 2(Et2mal) in MeCN leads to a nuclearity and oxidation level change to give (NBun4)2[Mn 8O4(O2CPh)12(Et2mal) 2(H2O)2] 1; the crystal structure and magnetochemical studies show the core of the anion to have a unique topology consisting of two linked [Mn4O2] butterfly units and to possess an S = 3 ground state, respectively.
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U2 - 10.1039/C39940001031
DO - 10.1039/C39940001031
M3 - Article
SP - 1031
EP - 1034
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 8
ER -