TY - JOUR
T1 - Hydrogen generation from hydrolysis of sodium borohydride using Ni-Ru nanocomposite as catalysts
AU - Liu, Cheng Hong
AU - Chen, Bing Hung
AU - Hsueh, Chan Li
AU - Ku, Jie Ren
AU - Jeng, Ming Shan
AU - Tsau, Fanghei
N1 - Funding Information:
The work was financially supported by the Bureau of Energy of the Ministry of Economic Affairs of the Republic of China (Taiwan) under Contract No. 97-D0136.
PY - 2009/3
Y1 - 2009/3
N2 - Magnetic nickel-ruthenium based catalysts on resin beads for hydrogen generation from alkaline NaBH4 solutions were synthesized with combined methods of chemical reduction and electroless deposition. Factors, such as solution temperature, NaBH4 loadings, and NaOH concentration, on performance of these catalysts on hydrogen production from alkaline NaBH4 solutions were investigated. Furthermore, characteristics of these nickel-ruthenium based catalysts were carried out by using various instruments, such as SEM/EDS, XPS, SQUID VSM and BET. These catalysts can be easily recycled from spent NaBH4 solution with permanent magnets owing to their intrinsic soft ferromagnetism and, therefore, reducing the operation cost of the hydrogen generation process. A rate of hydrogen evolution as high as ca. 400 mL min-1 g-1 could be reached at 35 °C in 10 wt% NaBH4 solution containing 5 wt% NaOH using Ni-Ru/50WX8 catalysts. Activation energy of hydrogen generation using such catalysts is estimated at 52.73 kJ mol-1.
AB - Magnetic nickel-ruthenium based catalysts on resin beads for hydrogen generation from alkaline NaBH4 solutions were synthesized with combined methods of chemical reduction and electroless deposition. Factors, such as solution temperature, NaBH4 loadings, and NaOH concentration, on performance of these catalysts on hydrogen production from alkaline NaBH4 solutions were investigated. Furthermore, characteristics of these nickel-ruthenium based catalysts were carried out by using various instruments, such as SEM/EDS, XPS, SQUID VSM and BET. These catalysts can be easily recycled from spent NaBH4 solution with permanent magnets owing to their intrinsic soft ferromagnetism and, therefore, reducing the operation cost of the hydrogen generation process. A rate of hydrogen evolution as high as ca. 400 mL min-1 g-1 could be reached at 35 °C in 10 wt% NaBH4 solution containing 5 wt% NaOH using Ni-Ru/50WX8 catalysts. Activation energy of hydrogen generation using such catalysts is estimated at 52.73 kJ mol-1.
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U2 - 10.1016/j.ijhydene.2008.12.059
DO - 10.1016/j.ijhydene.2008.12.059
M3 - Article
AN - SCOPUS:60649101220
VL - 34
SP - 2153
EP - 2163
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
SN - 0360-3199
IS - 5
ER -
