Hydrogen in layered iron arsenides: Indirect electron doping to induce superconductivity

Utilizing the high stability of calcium and rare-earth hydrides, CaFeAsF_1-xH_x (x = 0.0-1.0) and SmFeAsO_1-xH _x (x = 0.0-0.47) have been synthesized using high pressure to form hydrogen-substituted 1111-type iron-arsenide superconductors. Neutron diffraction and density functional calculations have demonstrated that the hydrogens are incorporated as H^- ions occupying F^- sites in the blocking layer of CaFeAsF. The resulting CaFeAsF_1-xH _x is nonsuperconducting, whereas, SmFeAsO_1-xH_x is a superconductor, with an optimal T_c = 55 K at x ∼ 0.2. It was found that up to 40% of the O2^- ions can be replaced by H ^- ions, with electrons being supplied into the FeAs layer to maintain neutrality (O2^- = H^- + e^-). When x exceeded 0.2, T_c was reduced corresponding to an electron overdoped region.