Hydrothermal corrosion of TiN PVD films on SUS-304

Sergiy Korablov; Masahiro Yoshimura

doi:10.1016/S0010-938X(02)00143-9

Hydrothermal corrosion of TiN PVD films on SUS-304

Sergiy Korablov
, Masahiro Yoshimura

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Hydrothermal corrosion of thin TiN PVD films (3 μm thickness) at 100 MPa water and 20-800°C temperature range was studied. Noticeable oxidation starts above 200°C and acceleration of oxidation processes takes place in hydrothermal conditions in comparison with airflow oxidation of corresponding PVD films and air oxidation of TiN powders. The formation of Ti_nO_2n-1 homological series phases and regular single crystals in oxide scale were observed. FeTiO₃ ilmenite layer secures high protective properties at 600°C and practically does not contain chromium. Therefore, usual low alloy steel with TiN coating can be used instead superalloy for wet air oxidation system with working temperature up to 600°C.

Original language	English
Pages (from-to)	531-543
Number of pages	13
Journal	Corrosion Science
Volume	45
Issue number	3
DOIs	https://doi.org/10.1016/S0010-938X(02)00143-9
Publication status	Published - 2003 Mar

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
General Materials Science

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10.1016/S0010-938X(02)00143-9

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title = "Hydrothermal corrosion of TiN PVD films on SUS-304",

abstract = "Hydrothermal corrosion of thin TiN PVD films (3 μm thickness) at 100 MPa water and 20-800°C temperature range was studied. Noticeable oxidation starts above 200°C and acceleration of oxidation processes takes place in hydrothermal conditions in comparison with airflow oxidation of corresponding PVD films and air oxidation of TiN powders. The formation of TinO2n-1 homological series phases and regular single crystals in oxide scale were observed. FeTiO3 ilmenite layer secures high protective properties at 600°C and practically does not contain chromium. Therefore, usual low alloy steel with TiN coating can be used instead superalloy for wet air oxidation system with working temperature up to 600°C.",

author = "Sergiy Korablov and Masahiro Yoshimura",

note = "Funding Information: This work was supported by Japan Society for Promotion of Science (JSPS), Project (\#96R06901). The authors are thankful to Drs. V. Petrykin, T. Fujwara, M. Ibrahim, Mr. T. Fujno and Mr. R. Teranishi for their helps in experiments.",

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doi = "10.1016/S0010-938X(02)00143-9",

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TY - JOUR

T1 - Hydrothermal corrosion of TiN PVD films on SUS-304

AU - Korablov, Sergiy

AU - Yoshimura, Masahiro

N1 - Funding Information: This work was supported by Japan Society for Promotion of Science (JSPS), Project (#96R06901). The authors are thankful to Drs. V. Petrykin, T. Fujwara, M. Ibrahim, Mr. T. Fujno and Mr. R. Teranishi for their helps in experiments.

PY - 2003/3

Y1 - 2003/3

N2 - Hydrothermal corrosion of thin TiN PVD films (3 μm thickness) at 100 MPa water and 20-800°C temperature range was studied. Noticeable oxidation starts above 200°C and acceleration of oxidation processes takes place in hydrothermal conditions in comparison with airflow oxidation of corresponding PVD films and air oxidation of TiN powders. The formation of TinO2n-1 homological series phases and regular single crystals in oxide scale were observed. FeTiO3 ilmenite layer secures high protective properties at 600°C and practically does not contain chromium. Therefore, usual low alloy steel with TiN coating can be used instead superalloy for wet air oxidation system with working temperature up to 600°C.

AB - Hydrothermal corrosion of thin TiN PVD films (3 μm thickness) at 100 MPa water and 20-800°C temperature range was studied. Noticeable oxidation starts above 200°C and acceleration of oxidation processes takes place in hydrothermal conditions in comparison with airflow oxidation of corresponding PVD films and air oxidation of TiN powders. The formation of TinO2n-1 homological series phases and regular single crystals in oxide scale were observed. FeTiO3 ilmenite layer secures high protective properties at 600°C and practically does not contain chromium. Therefore, usual low alloy steel with TiN coating can be used instead superalloy for wet air oxidation system with working temperature up to 600°C.

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U2 - 10.1016/S0010-938X(02)00143-9

DO - 10.1016/S0010-938X(02)00143-9

M3 - Article

AN - SCOPUS:0037340729

SN - 0010-938X

VL - 45

SP - 531

EP - 543

JO - Corrosion Science

JF - Corrosion Science

IS - 3

ER -

Hydrothermal corrosion of TiN PVD films on SUS-304

Abstract

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