Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks

Yen Hsiang Liu, Chia Shiang Lin, Shiang Ying Chen, Hui-Lien Tsai, Chuen Her Ueng, Kuang Lieh Lu

Research output: Contribution to journalArticle

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Abstract

Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.

Original languageEnglish
Pages (from-to)166-172
Number of pages7
JournalJournal of Solid State Chemistry
Volume157
Issue number1
DOIs
Publication statusPublished - 2001 Jan 1

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Hydrothermal synthesis
Interpenetrating polymer networks
Crystal structure
Metals
Crystals
crystal structure
synthesis
Single crystals
X ray analysis
crystals
metal compounds
single crystals
Ligands
metals
X ray diffraction
Molecules
x rays
grids
inclusions
ligands

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Liu, Yen Hsiang ; Lin, Chia Shiang ; Chen, Shiang Ying ; Tsai, Hui-Lien ; Ueng, Chuen Her ; Lu, Kuang Lieh. / Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks. In: Journal of Solid State Chemistry. 2001 ; Vol. 157, No. 1. pp. 166-172.
@article{783bea8653354f35b8b11f7d2e56f185,
title = "Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks",
abstract = "Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) {\AA}, b=6.995(2) {\AA}, c=16.723(3) {\AA}, V=1606.7(6) {\AA}3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) {\AA}, b=21.2838(16) {\AA}, c=8.5504(7) {\AA}, β=130.5210(10)°, V=1600.8(2) {\AA}3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) {\AA}, b=7.5053(8) {\AA}, c=15.929(4) A, V=1636.0(5) {\AA}3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.",
author = "Liu, {Yen Hsiang} and Lin, {Chia Shiang} and Chen, {Shiang Ying} and Hui-Lien Tsai and Ueng, {Chuen Her} and Lu, {Kuang Lieh}",
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Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks. / Liu, Yen Hsiang; Lin, Chia Shiang; Chen, Shiang Ying; Tsai, Hui-Lien; Ueng, Chuen Her; Lu, Kuang Lieh.

In: Journal of Solid State Chemistry, Vol. 157, No. 1, 01.01.2001, p. 166-172.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks

AU - Liu, Yen Hsiang

AU - Lin, Chia Shiang

AU - Chen, Shiang Ying

AU - Tsai, Hui-Lien

AU - Ueng, Chuen Her

AU - Lu, Kuang Lieh

PY - 2001/1/1

Y1 - 2001/1/1

N2 - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.

AB - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.

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