TY - JOUR
T1 - Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks
AU - Liu, Yen Hsiang
AU - Lin, Chia Shiang
AU - Chen, Shiang Ying
AU - Tsai, Hui Lien
AU - Ueng, Chuen Her
AU - Lu, Kuang Lieh
N1 - Funding Information:
We thank the Institute of Chemistry, Academia Sinica, and National Science Council for supporting this work, and Mr. Ting-Shen Kuo at National Taiwan Normal University and Prof. Ju-Chun Wang at Soochow University, Taipei, for their assistance with crystallographic work.
Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 2001
Y1 - 2001
N2 - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.
AB - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.
UR - http://www.scopus.com/inward/record.url?scp=0034804639&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034804639&partnerID=8YFLogxK
U2 - 10.1006/jssc.2000.9070
DO - 10.1006/jssc.2000.9070
M3 - Article
AN - SCOPUS:0034804639
VL - 157
SP - 166
EP - 172
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 1
ER -