Abstract
Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.
| Original language | English |
|---|---|
| Pages (from-to) | 166-172 |
| Number of pages | 7 |
| Journal | Journal of Solid State Chemistry |
| Volume | 157 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2001 Jan 1 |
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All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Condensed Matter Physics
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
Cite this
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Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks. / Liu, Yen Hsiang; Lin, Chia Shiang; Chen, Shiang Ying; Tsai, Hui-Lien; Ueng, Chuen Her; Lu, Kuang Lieh.
In: Journal of Solid State Chemistry, Vol. 157, No. 1, 01.01.2001, p. 166-172.Research output: Contribution to journal › Article
TY - JOUR
T1 - Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks
AU - Liu, Yen Hsiang
AU - Lin, Chia Shiang
AU - Chen, Shiang Ying
AU - Tsai, Hui-Lien
AU - Ueng, Chuen Her
AU - Lu, Kuang Lieh
PY - 2001/1/1
Y1 - 2001/1/1
N2 - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.
AB - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.
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U2 - 10.1006/jssc.2000.9070
DO - 10.1006/jssc.2000.9070
M3 - Article
VL - 157
SP - 166
EP - 172
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 1
ER -