Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks

Yen Hsiang Liu; Chia Shiang Lin; Shiang Ying Chen; Hui Lien Tsai; Chuen Her Ueng; Kuang Lieh Lu

doi:10.1006/jssc.2000.9070

Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks

Yen Hsiang Liu, Chia Shiang Lin, Shiang Ying Chen, Hui Lien Tsai, Chuen Her Ueng, Kuang Lieh Lu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Three metal-organic polymeric networks, Ni(C₈H₆NO₂)₂ (H₂O)₂ (1), Co(C₈H₆NO₂)₂ (2), and Cu(C₈H₆NO₂)₂(H₂O) ₂ (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å³, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å³, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å³, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.

Original language	English
Pages (from-to)	166-172
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	157
Issue number	1
DOIs	https://doi.org/10.1006/jssc.2000.9070
Publication status	Published - 2001 Jan 1

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{783bea8653354f35b8b11f7d2e56f185,

title = "Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks",

abstract = "Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) {\AA}, b=6.995(2) {\AA}, c=16.723(3) {\AA}, V=1606.7(6) {\AA}3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) {\AA}, b=21.2838(16) {\AA}, c=8.5504(7) {\AA}, β=130.5210(10)°, V=1600.8(2) {\AA}3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) {\AA}, b=7.5053(8) {\AA}, c=15.929(4) A, V=1636.0(5) {\AA}3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.",

author = "Liu, {Yen Hsiang} and Lin, {Chia Shiang} and Chen, {Shiang Ying} and Tsai, {Hui Lien} and Ueng, {Chuen Her} and Lu, {Kuang Lieh}",

year = "2001",

month = jan,

day = "1",

doi = "10.1006/jssc.2000.9070",

language = "English",

volume = "157",

pages = "166--172",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "1",

}

Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks. / Liu, Yen Hsiang; Lin, Chia Shiang; Chen, Shiang Ying; Tsai, Hui Lien; Ueng, Chuen Her; Lu, Kuang Lieh.

In: Journal of Solid State Chemistry, Vol. 157, No. 1, 01.01.2001, p. 166-172.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal syntheses and crystal structures of Ni(II), Co(II), and Cu(II), bis(trans-4-pyridylacrylate)interpenetration networks

AU - Liu, Yen Hsiang

AU - Lin, Chia Shiang

AU - Chen, Shiang Ying

AU - Tsai, Hui Lien

AU - Ueng, Chuen Her

AU - Lu, Kuang Lieh

PY - 2001/1/1

Y1 - 2001/1/1

N2 - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.

AB - Three metal-organic polymeric networks, Ni(C8H6NO2)2 (H2O)2 (1), Co(C8H6NO2)2 (2), and Cu(C8H6NO2)2(H2O) 2 (3), were synthesized by the hydrothermal method. Single-crystal X-ray analysis revealed that within these compounds metal centers are linked through trans-4-pyridylacrylate ligands to form interpenetrating infinite networks. The Ni(II) and Cu(II) compounds possess an overlay of interpenetrating square grid layers, whereas the Co(II) compound possesses interpenetrating diamondoid networks. Comparing these three compounds, the formation of cavities potentially for guest molecule inclusion within the interpenetrating networks could be achieved by taking advantage of the coordination nature of metals. Crystal structures of all three compounds were determined by single-crystal X-ray diffraction methods and solved by direct method. Crystal data for 1: orthorhombic, space group Pbcn, a=13.735(3) Å, b=6.995(2) Å, c=16.723(3) Å, V=1606.7(6) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0296, wR2=0.0843. Crystal data for 2: monoclinic, space group Cc, a=11.5717(9) Å, b=21.2838(16) Å, c=8.5504(7) Å, β=130.5210(10)°, V=1600.8(2) Å3, Z=4, final refinement (I>2σ(I)): R1=0.0347, wR2=0.0879. Crystal data for 3: orthorhomhic, space group Pbcn, a=13.6844(13) Å, b=7.5053(8) Å, c=15.929(4) A, V=1636.0(5) Å3, Z=4, final refinement (I>2σ(I)), R1=0.0299, wR2=0.0787.

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U2 - 10.1006/jssc.2000.9070

DO - 10.1006/jssc.2000.9070

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JO - Journal of Solid State Chemistry

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