Improved conversion efficiency of perovskite solar cells converted from thermally deposited lead iodide with dimethyl sulfoxide-treated poly(3,4-ethylenedioxythiophene) poly(styrene sulfonate)

Wei-Chi Lai, Huai Cheng Yu, Siou Huei Yang, Tzung-Fang Guo, Peter Chen, Li Jyuan Lin, Hsu-Cheng Hsu, Anupriya Singh, Chih Wei Chu

Research output: Contribution to journalArticle

Abstract

The thermal deposition of lead iodide (PbI2) results in the changes in the contact surface of a poly (3,4-ethylenedioxythiophene) poly (styrene sulfonate) (PEDOT:PSS) layer of solar cells (SCs). The changed contact surface of PEDOT:PSS layer after the thermal deposition of PbI2 remains stable after PbI2 is converted into perovskite and leaves the degraded perovskite/PEDOT:PSS interface. The degraded perovskite/pristine PEDOT:PSS interface leads to a low power conversion efficiency (η%) of SCs at 3.84%. The properties of the contact surface of the PEDOT:PSS layer during the thermal deposition of PbI2 can be retained by treating PEDOT:PSS with dimethyl sulfoxide (DMSO) and maintain the perovskite/PEDOT:PSS interface in good condition after PbI2 is converted. Perovskite SCs with DMSO-treated PEDOT:PSS substantially improves η% from 3.84% to 9.58%.

Original languageEnglish
Pages (from-to)266-272
Number of pages7
JournalOrganic Electronics
Volume73
DOIs
Publication statusPublished - 2019 Oct

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All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry
  • Electrical and Electronic Engineering

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