Influence of LiTFSI addition on conductivity, diffusion coefficient, Spin-lattice relaxation times, and chemical shift of one-dimensional NMR spectroscopy in LiTFSI -doped dual-functionalized imidazolium-based ionic liquids

Tzi Yi Wu, Yi Hsuan Wang, Shyh-Gang Su, Yuan Chung Lin, Chung Wen Kuo, Jeng Kuei Chang, I-Wen Sun

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

An ionic liquid (IL) 1-allyl-3-(2-methoxyethyl)imidazolium bis(trifluoromethylsulfonyl)imide ([AMO][TFSI]) is prepared, and the effect of the addition of LiTFSI into [AMO][TFSI] on the transport and physicochemical properties is studied herein. The diffusion coefficients of 1 H, 7 Li, and 19 F are determined using pulsed-gradient spin-echo NMR to study the dynamics of all ion species. The neat [AMO][TFSI] and LiTFSI-doped [AMO][TFSI] give approximately straight lines for the relationship of D vs T• -1 , demonstrating that the Stokes-Einstein equation holds for the ionic diffusivity in the binary system. NMR T 1 relation time measurements show the 1 H-T 1 and 19 F-T 1 of LiTFSI-doped [AMO][TFSI] decrease with the increase of Li salt concentration, which is due to the viscosity increases and the formation of stable coordination adducts of Li and TFSI when the salt concentration increases. From the study of chemical shift in one-dimensional NMR spectroscopy, an upfield shift in 1 H and 19 F spectra is observed in ILs with increasing lithium salt concentration; the formation of ion clusters is the dominant effect after the addition of LiTFSI in [AMO][TFSI].

Original languageEnglish
Pages (from-to)471-483
Number of pages13
JournalJournal of Chemical and Engineering Data
Volume60
Issue number3
DOIs
Publication statusPublished - 2015 Mar 12

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Ionic Liquids
Spin-lattice relaxation
Chemical shift
Ionic liquids
Relaxation time
Nuclear magnetic resonance spectroscopy
Salts
Nuclear magnetic resonance
Ions
Imides
Time measurement
Lithium
Viscosity

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

@article{0073b4e4622a4b7c85296cd4976f091b,
title = "Influence of LiTFSI addition on conductivity, diffusion coefficient, Spin-lattice relaxation times, and chemical shift of one-dimensional NMR spectroscopy in LiTFSI -doped dual-functionalized imidazolium-based ionic liquids",
abstract = "An ionic liquid (IL) 1-allyl-3-(2-methoxyethyl)imidazolium bis(trifluoromethylsulfonyl)imide ([AMO][TFSI]) is prepared, and the effect of the addition of LiTFSI into [AMO][TFSI] on the transport and physicochemical properties is studied herein. The diffusion coefficients of 1 H, 7 Li, and 19 F are determined using pulsed-gradient spin-echo NMR to study the dynamics of all ion species. The neat [AMO][TFSI] and LiTFSI-doped [AMO][TFSI] give approximately straight lines for the relationship of D vs T• -1 , demonstrating that the Stokes-Einstein equation holds for the ionic diffusivity in the binary system. NMR T 1 relation time measurements show the 1 H-T 1 and 19 F-T 1 of LiTFSI-doped [AMO][TFSI] decrease with the increase of Li salt concentration, which is due to the viscosity increases and the formation of stable coordination adducts of Li and TFSI when the salt concentration increases. From the study of chemical shift in one-dimensional NMR spectroscopy, an upfield shift in 1 H and 19 F spectra is observed in ILs with increasing lithium salt concentration; the formation of ion clusters is the dominant effect after the addition of LiTFSI in [AMO][TFSI].",
author = "Wu, {Tzi Yi} and Wang, {Yi Hsuan} and Shyh-Gang Su and Lin, {Yuan Chung} and Kuo, {Chung Wen} and Chang, {Jeng Kuei} and I-Wen Sun",
year = "2015",
month = "3",
day = "12",
doi = "10.1021/je500431h",
language = "English",
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pages = "471--483",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
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TY - JOUR

T1 - Influence of LiTFSI addition on conductivity, diffusion coefficient, Spin-lattice relaxation times, and chemical shift of one-dimensional NMR spectroscopy in LiTFSI -doped dual-functionalized imidazolium-based ionic liquids

AU - Wu, Tzi Yi

AU - Wang, Yi Hsuan

AU - Su, Shyh-Gang

AU - Lin, Yuan Chung

AU - Kuo, Chung Wen

AU - Chang, Jeng Kuei

AU - Sun, I-Wen

PY - 2015/3/12

Y1 - 2015/3/12

N2 - An ionic liquid (IL) 1-allyl-3-(2-methoxyethyl)imidazolium bis(trifluoromethylsulfonyl)imide ([AMO][TFSI]) is prepared, and the effect of the addition of LiTFSI into [AMO][TFSI] on the transport and physicochemical properties is studied herein. The diffusion coefficients of 1 H, 7 Li, and 19 F are determined using pulsed-gradient spin-echo NMR to study the dynamics of all ion species. The neat [AMO][TFSI] and LiTFSI-doped [AMO][TFSI] give approximately straight lines for the relationship of D vs T• -1 , demonstrating that the Stokes-Einstein equation holds for the ionic diffusivity in the binary system. NMR T 1 relation time measurements show the 1 H-T 1 and 19 F-T 1 of LiTFSI-doped [AMO][TFSI] decrease with the increase of Li salt concentration, which is due to the viscosity increases and the formation of stable coordination adducts of Li and TFSI when the salt concentration increases. From the study of chemical shift in one-dimensional NMR spectroscopy, an upfield shift in 1 H and 19 F spectra is observed in ILs with increasing lithium salt concentration; the formation of ion clusters is the dominant effect after the addition of LiTFSI in [AMO][TFSI].

AB - An ionic liquid (IL) 1-allyl-3-(2-methoxyethyl)imidazolium bis(trifluoromethylsulfonyl)imide ([AMO][TFSI]) is prepared, and the effect of the addition of LiTFSI into [AMO][TFSI] on the transport and physicochemical properties is studied herein. The diffusion coefficients of 1 H, 7 Li, and 19 F are determined using pulsed-gradient spin-echo NMR to study the dynamics of all ion species. The neat [AMO][TFSI] and LiTFSI-doped [AMO][TFSI] give approximately straight lines for the relationship of D vs T• -1 , demonstrating that the Stokes-Einstein equation holds for the ionic diffusivity in the binary system. NMR T 1 relation time measurements show the 1 H-T 1 and 19 F-T 1 of LiTFSI-doped [AMO][TFSI] decrease with the increase of Li salt concentration, which is due to the viscosity increases and the formation of stable coordination adducts of Li and TFSI when the salt concentration increases. From the study of chemical shift in one-dimensional NMR spectroscopy, an upfield shift in 1 H and 19 F spectra is observed in ILs with increasing lithium salt concentration; the formation of ion clusters is the dominant effect after the addition of LiTFSI in [AMO][TFSI].

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