Inter- and intramolecular alcohol additions to exo-glycals

Chuan-Fa Chang, Wen Bin Yang, Che Chien Chang, Chun Hung Lin

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Various exo-glycals were explored for the glycosidic bond formation and synthesis of spiroacetals in a stereoselective manner. The former reaction was an intermolecular alcohol addition to give the S new stereogenic center, resulting from the nucleophilic attack from the bottom face of the sugar ring. The latter one was carried out by the hydroboration of a sugar diene, followed by a subsequent acid workup.

Original languageEnglish
Pages (from-to)6515-6519
Number of pages5
JournalTetrahedron Letters
Volume43
Issue number37
DOIs
Publication statusPublished - 2002 Sep 9

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Sugars
Alcohols
Acids

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Chang, Chuan-Fa ; Yang, Wen Bin ; Chang, Che Chien ; Lin, Chun Hung. / Inter- and intramolecular alcohol additions to exo-glycals. In: Tetrahedron Letters. 2002 ; Vol. 43, No. 37. pp. 6515-6519.
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Inter- and intramolecular alcohol additions to exo-glycals. / Chang, Chuan-Fa; Yang, Wen Bin; Chang, Che Chien; Lin, Chun Hung.

In: Tetrahedron Letters, Vol. 43, No. 37, 09.09.2002, p. 6515-6519.

Research output: Contribution to journalArticle

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