Interaction between hydrophobically modified 2-hydroxyethyl cellulose and sodium dodecyl sulfate studied by viscometry and two-dimensional NOE NMR spectroscopy

Jen Ting Lo, Hsiao Ting Yen, Chih Chang Tsai, Bing Hung Chen, Sheng Shu Hou

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Interaction between an anionic surfactant, sodium dodecyl sulfate (SDS), and a nonionic polymer, 2-hydroxyethyl cellulose (HEC) hydrophobically modified with benzoyl chloride (bmHEC), is studied by viscometry and two-dimensional nuclear Overhauser effect NMR spectroscopy (2D NOESY) in a semidilute regime of bmHEC. The hydrophobicity of bmHEC was varied with different substitution of benzoyl group to HEC macromolecules. In general, the low-shear viscosity of 1 wt % bmHEC aqueous solution is increased with added SDS surfactant having concentration from 0 to 0.5 wt %, and then decreased significantly with a further addition of surfactant to 3 wt %. The activation energy of transient network formation in 1 wt % bmHEC aqueous solution present with SDS surfactant is found to be dependent with SDS concentration, which varies from 32.7 to 69.80 kJ/mol. The maximum activation energy takes place when 0.5 wt % SDS is added, which coincides with that of the maximal viscosity. The 2D NOESY displays that the surfactants actually interact with bmHEC not only on the hydrophobes, namely benzoyl groups, but also the polymer backbone, i.e., glucose units. In contrast, no interaction is revealed by 2D NOESY in the aqueous system containing SDS surfactant and HEC polymer.

Original languageEnglish
Pages (from-to)6922-6930
Number of pages9
JournalJournal of Physical Chemistry B
Volume118
Issue number24
DOIs
Publication statusPublished - 2014 Jun 19

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viscometry
Viscosity measurement
Sodium dodecyl sulfate
sodium sulfates
cellulose
Cellulose
Sodium Dodecyl Sulfate
Nuclear magnetic resonance spectroscopy
Surface-Active Agents
surfactants
Surface active agents
nuclear magnetic resonance
spectroscopy
Polymers
interactions
polymers
Activation energy
viscosity
activation energy
Overhauser effect

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

@article{accf282465ac4b0e8adb5878fed764ba,
title = "Interaction between hydrophobically modified 2-hydroxyethyl cellulose and sodium dodecyl sulfate studied by viscometry and two-dimensional NOE NMR spectroscopy",
abstract = "Interaction between an anionic surfactant, sodium dodecyl sulfate (SDS), and a nonionic polymer, 2-hydroxyethyl cellulose (HEC) hydrophobically modified with benzoyl chloride (bmHEC), is studied by viscometry and two-dimensional nuclear Overhauser effect NMR spectroscopy (2D NOESY) in a semidilute regime of bmHEC. The hydrophobicity of bmHEC was varied with different substitution of benzoyl group to HEC macromolecules. In general, the low-shear viscosity of 1 wt {\%} bmHEC aqueous solution is increased with added SDS surfactant having concentration from 0 to 0.5 wt {\%}, and then decreased significantly with a further addition of surfactant to 3 wt {\%}. The activation energy of transient network formation in 1 wt {\%} bmHEC aqueous solution present with SDS surfactant is found to be dependent with SDS concentration, which varies from 32.7 to 69.80 kJ/mol. The maximum activation energy takes place when 0.5 wt {\%} SDS is added, which coincides with that of the maximal viscosity. The 2D NOESY displays that the surfactants actually interact with bmHEC not only on the hydrophobes, namely benzoyl groups, but also the polymer backbone, i.e., glucose units. In contrast, no interaction is revealed by 2D NOESY in the aqueous system containing SDS surfactant and HEC polymer.",
author = "Lo, {Jen Ting} and Yen, {Hsiao Ting} and Tsai, {Chih Chang} and Chen, {Bing Hung} and Hou, {Sheng Shu}",
year = "2014",
month = "6",
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Interaction between hydrophobically modified 2-hydroxyethyl cellulose and sodium dodecyl sulfate studied by viscometry and two-dimensional NOE NMR spectroscopy. / Lo, Jen Ting; Yen, Hsiao Ting; Tsai, Chih Chang; Chen, Bing Hung; Hou, Sheng Shu.

In: Journal of Physical Chemistry B, Vol. 118, No. 24, 19.06.2014, p. 6922-6930.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Interaction between hydrophobically modified 2-hydroxyethyl cellulose and sodium dodecyl sulfate studied by viscometry and two-dimensional NOE NMR spectroscopy

AU - Lo, Jen Ting

AU - Yen, Hsiao Ting

AU - Tsai, Chih Chang

AU - Chen, Bing Hung

AU - Hou, Sheng Shu

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