Interface-induced superconductivity at ∼25 K at ambient pressure in undoped CaFe2As2 single crystals

Kui Zhao, Bing Lv, Liangzi Deng, Shu Yuan Huyan, Yu Yi Xue, Ching Wu Chu

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18 Citations (Scopus)


Superconductivity has been reversibly induced/suppressed in undoped CaFe2As2 (Ca122) single crystals through proper thermal treatments, with Tc at ∼25 K at ambient pressure and up to 30 K at 1.7 GPa. We found that Ca122 can be stabilized in two distinct tetragonal (T) phases at room temperature and ambient pressure: PI with a nonmagnetic collapsed tetragonal (cT) phase at low temperature and PII with an antiferromagnetic orthorhombic (O) phase at low temperature, depending on the low-temperature annealing condition. Neither phase at ambient pressure is superconducting down to 2 K. However, systematic annealing for different time periods at 350°C on the as-synthesized crystals, which were obtained by quenching the crystal ingot from 850°C, reveals the emergence of superconductivity over a narrow time window. Whereas the onset Tc is insensitive to the anneal time, the superconductive volume fraction evolves with the time in a dome-shaped fashion. Detailed X-ray diffraction profile analyses further reveal mesoscopically stacked layers of the PI and the PII phases. The deduced interface density correlates well with the superconducting volume measured. The transport anomalies of the T-cT transition, which is sensitive to lattice strain, and the T-O transition, which is associated with the spin-density-wave (SDW) transition, are gradually suppressed over the superconductive region, presumably due to the interface interactions between the nonmagnetic metallic cT phase and the antiferromagnetic O phase. The results provide the most direct evidence to date for interface-enhanced superconductivity in undoped Ca122, consistent with the recent theoretical prediction.

Original languageEnglish
Pages (from-to)12968-12973
Number of pages6
JournalProceedings of the National Academy of Sciences of the United States of America
Issue number46
Publication statusPublished - 2016 Nov 15

All Science Journal Classification (ASJC) codes

  • General


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