TY - JOUR
T1 - Ionic-liquid-crafted zeolite for the removal of anionic dye methyl orange
AU - Xing, Xuebing
AU - Chang, Po Hsiang
AU - Lv, Guocheng
AU - Jiang, Wei Teh
AU - Jean, Jiin Shuh
AU - Liao, Libing
AU - Li, Zhaohui
N1 - Funding Information:
This research was supported by the following grants: (1) International Science and Technology Cooperation of China ( 2014DFA91000 ), (2) MOST 104-2811-M-006-001 and 103-2116-M-006-001 to Jiang from the Ministry of Science and Technology, Taiwan , (3) Beijing Natural Science Foundation ( 2153041 ), (4) Beijing Higher Education Young Elite Teacher Project ( YETP0634 ), (5) Wisconsin Groundwater Research Council, and (6) CAS/SAFEA International Partnership Program for Creative Research Teams 20140491534 . Proofread and English improvements were made possible with the help of Nicole Fitzgerald of University of Wisconsin–Parkside.
Publisher Copyright:
© 2015 Taiwan Institute of Chemical Engineers.
PY - 2016/2/1
Y1 - 2016/2/1
N2 - In this study a clinoptilolite zeolite was modified by an ionic liquid 1-hexadecyl-3-methylimidazolium chloride monohydrate to 1.0 and 2.0 times its external cation exchange capacity (ECEC). The ionic-liquid-crafted zeolite (ILCZ) was tested for its removal of anionic dyes from solution using methyl orange (MO) as an example. The uptake of MO was fast and followed a pseudo-second-order kinetics with MO adsorption capacities of 45 and 116 mmol/kg on ILCZ modified to 1.0 and 2.0 ECEC, respectively. Stoichiometric desorption of counterion chloride accompanying MO uptake suggested an anion exchange mechanism of MO uptake on ILCZ modified to 2.0 ECEC. Solution pH in the range of 2-11 and ionic strength in the range of 0.001-0.01 M of background salt concentrations of varying charges had minimal effects on MO uptake, suggesting higher affinity of MO for ILCZ in comparison to other inorganic anions. As the MO adsorption capacity on ILCZ modified to 2.0 ECEC was about the same as the ECEC of the zeolite, the mechanism of removal of anionic dyes was attributed to surface anion exchange resulted from the positively charged ILCZ surfaces due to a bilayer IL formation on zeolite after being modified to 2.0 ECEC. In contrast, patchy admicelles of IL would form on zeolite after being modified to 1.0 ECEC, resulting in reduced MO uptake. The contrasting behaviors of IL modification on zeolite and subsequent MO adsorption on ILCZ suggested that modification of ILCZ to 2.0 ECEC was necessary for ILCZ to serve as a sorbent material for the removal of anionic dyes from solution.
AB - In this study a clinoptilolite zeolite was modified by an ionic liquid 1-hexadecyl-3-methylimidazolium chloride monohydrate to 1.0 and 2.0 times its external cation exchange capacity (ECEC). The ionic-liquid-crafted zeolite (ILCZ) was tested for its removal of anionic dyes from solution using methyl orange (MO) as an example. The uptake of MO was fast and followed a pseudo-second-order kinetics with MO adsorption capacities of 45 and 116 mmol/kg on ILCZ modified to 1.0 and 2.0 ECEC, respectively. Stoichiometric desorption of counterion chloride accompanying MO uptake suggested an anion exchange mechanism of MO uptake on ILCZ modified to 2.0 ECEC. Solution pH in the range of 2-11 and ionic strength in the range of 0.001-0.01 M of background salt concentrations of varying charges had minimal effects on MO uptake, suggesting higher affinity of MO for ILCZ in comparison to other inorganic anions. As the MO adsorption capacity on ILCZ modified to 2.0 ECEC was about the same as the ECEC of the zeolite, the mechanism of removal of anionic dyes was attributed to surface anion exchange resulted from the positively charged ILCZ surfaces due to a bilayer IL formation on zeolite after being modified to 2.0 ECEC. In contrast, patchy admicelles of IL would form on zeolite after being modified to 1.0 ECEC, resulting in reduced MO uptake. The contrasting behaviors of IL modification on zeolite and subsequent MO adsorption on ILCZ suggested that modification of ILCZ to 2.0 ECEC was necessary for ILCZ to serve as a sorbent material for the removal of anionic dyes from solution.
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U2 - 10.1016/j.jtice.2015.07.026
DO - 10.1016/j.jtice.2015.07.026
M3 - Article
AN - SCOPUS:84958122332
VL - 59
SP - 237
EP - 243
JO - Journal of the Taiwan Institute of Chemical Engineers
JF - Journal of the Taiwan Institute of Chemical Engineers
SN - 1876-1070
ER -