Large scale and orientation-controllable nanotip structures on CuInS 2, Cu(In,Ga)S2, CuInSe2, and Cu(In,Ga)Se 2 by low energy ion beam bombardment process: Growth and characterization

Yu Ting Yen; Yi Chung Wang; Yu Ze Chen; Hung Wei Tsai; Fan Hu; Shih Ming Lin; Yi Ju Chen; Chih Chung Lai; Wenlong Liu; Tsang Hsiu Wang; Hwen Fen Hong; Yu Lun Chueh

doi:10.1021/am501161j

Large scale and orientation-controllable nanotip structures on CuInS ₂, Cu(In,Ga)S₂, CuInSe₂, and Cu(In,Ga)Se ₂ by low energy ion beam bombardment process: Growth and characterization

Yu Ting Yen, Yi Chung Wang, Yu Ze Chen, Hung Wei Tsai, Fan Hu, Shih Ming Lin, Yi Ju Chen, Chih Chung Lai, Wenlong Liu, Tsang Hsiu Wang, Hwen Fen Hong, Yu Lun Chueh

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

One-step facile methodology to create nanotip arrays on chalcopyrite materials (such as CuInS₂, Cu(In,Ga)S₂, CuInSe ₂, and Cu(In,Ga)Se₂) via a low energy ion beam bombardment process has been demonstrated. The mechanism of formation for nanotip arrays has been proposed by sputtering yields of metals and reduction of metals induced by the ion beam bombardment process. The optical reflectance of these chalcopyrite nanotip arrays has been characterized by UV-vis spectrophotometer and the efficient light-trapping effect has been observed. Large scale (∼4′′) and high density (10¹⁰ tips/cm²) of chalcopyrite nanotip arrays have been obtained by using low ion energy (< 1 kV), short processing duration (< 30 min), and template-free. Besides, orientation and length of these chalcopyrite nanotip arrays are controllable. Our results can be the guide for other nanostructured materials fabrication by ion sputtering and are available for industrial production as well.

Original language	English
Pages (from-to)	8327-8336
Number of pages	10
Journal	ACS Applied Materials and Interfaces
Volume	6
Issue number	11
DOIs	https://doi.org/10.1021/am501161j
Publication status	Published - 2014 Jun 11

All Science Journal Classification (ASJC) codes

General Materials Science

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10.1021/am501161j

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Yen, Y. T., Wang, Y. C., Chen, Y. Z., Tsai, H. W., Hu, F., Lin, S. M., Chen, Y. J., Lai, C. C., Liu, W., Wang, T. H., Hong, H. F., & Chueh, Y. L. (2014). Large scale and orientation-controllable nanotip structures on CuInS ₂, Cu(In,Ga)S₂, CuInSe₂, and Cu(In,Ga)Se ₂ by low energy ion beam bombardment process: Growth and characterization. ACS Applied Materials and Interfaces, 6(11), 8327-8336. https://doi.org/10.1021/am501161j

@article{e8620ae7283147ddbdf9ed5f61d4db0f,

title = "Large scale and orientation-controllable nanotip structures on CuInS 2, Cu(In,Ga)S2, CuInSe2, and Cu(In,Ga)Se 2 by low energy ion beam bombardment process: Growth and characterization",

abstract = "One-step facile methodology to create nanotip arrays on chalcopyrite materials (such as CuInS2, Cu(In,Ga)S2, CuInSe 2, and Cu(In,Ga)Se2) via a low energy ion beam bombardment process has been demonstrated. The mechanism of formation for nanotip arrays has been proposed by sputtering yields of metals and reduction of metals induced by the ion beam bombardment process. The optical reflectance of these chalcopyrite nanotip arrays has been characterized by UV-vis spectrophotometer and the efficient light-trapping effect has been observed. Large scale (∼4′′) and high density (1010 tips/cm2) of chalcopyrite nanotip arrays have been obtained by using low ion energy (< 1 kV), short processing duration (< 30 min), and template-free. Besides, orientation and length of these chalcopyrite nanotip arrays are controllable. Our results can be the guide for other nanostructured materials fabrication by ion sputtering and are available for industrial production as well.",

author = "Yen, {Yu Ting} and Wang, {Yi Chung} and Chen, {Yu Ze} and Tsai, {Hung Wei} and Fan Hu and Lin, {Shih Ming} and Chen, {Yi Ju} and Lai, {Chih Chung} and Wenlong Liu and Wang, {Tsang Hsiu} and Hong, {Hwen Fen} and Chueh, {Yu Lun}",

year = "2014",

month = jun,

day = "11",

doi = "10.1021/am501161j",

language = "English",

volume = "6",

pages = "8327--8336",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "11",

}

Yen, YT, Wang, YC, Chen, YZ, Tsai, HW, Hu, F, Lin, SM, Chen, YJ, Lai, CC, Liu, W, Wang, TH, Hong, HF & Chueh, YL 2014, 'Large scale and orientation-controllable nanotip structures on CuInS ₂, Cu(In,Ga)S₂, CuInSe₂, and Cu(In,Ga)Se ₂ by low energy ion beam bombardment process: Growth and characterization', ACS Applied Materials and Interfaces, vol. 6, no. 11, pp. 8327-8336. https://doi.org/10.1021/am501161j

Large scale and orientation-controllable nanotip structures on CuInS ₂, Cu(In,Ga)S₂, CuInSe₂, and Cu(In,Ga)Se ₂ by low energy ion beam bombardment process: Growth and characterization. / Yen, Yu Ting; Wang, Yi Chung; Chen, Yu Ze et al.
In: ACS Applied Materials and Interfaces, Vol. 6, No. 11, 11.06.2014, p. 8327-8336.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Large scale and orientation-controllable nanotip structures on CuInS 2, Cu(In,Ga)S2, CuInSe2, and Cu(In,Ga)Se 2 by low energy ion beam bombardment process

T2 - Growth and characterization

AU - Yen, Yu Ting

AU - Wang, Yi Chung

AU - Chen, Yu Ze

AU - Tsai, Hung Wei

AU - Hu, Fan

AU - Lin, Shih Ming

AU - Chen, Yi Ju

AU - Lai, Chih Chung

AU - Liu, Wenlong

AU - Wang, Tsang Hsiu

AU - Hong, Hwen Fen

AU - Chueh, Yu Lun

PY - 2014/6/11

Y1 - 2014/6/11

N2 - One-step facile methodology to create nanotip arrays on chalcopyrite materials (such as CuInS2, Cu(In,Ga)S2, CuInSe 2, and Cu(In,Ga)Se2) via a low energy ion beam bombardment process has been demonstrated. The mechanism of formation for nanotip arrays has been proposed by sputtering yields of metals and reduction of metals induced by the ion beam bombardment process. The optical reflectance of these chalcopyrite nanotip arrays has been characterized by UV-vis spectrophotometer and the efficient light-trapping effect has been observed. Large scale (∼4′′) and high density (1010 tips/cm2) of chalcopyrite nanotip arrays have been obtained by using low ion energy (< 1 kV), short processing duration (< 30 min), and template-free. Besides, orientation and length of these chalcopyrite nanotip arrays are controllable. Our results can be the guide for other nanostructured materials fabrication by ion sputtering and are available for industrial production as well.

AB - One-step facile methodology to create nanotip arrays on chalcopyrite materials (such as CuInS2, Cu(In,Ga)S2, CuInSe 2, and Cu(In,Ga)Se2) via a low energy ion beam bombardment process has been demonstrated. The mechanism of formation for nanotip arrays has been proposed by sputtering yields of metals and reduction of metals induced by the ion beam bombardment process. The optical reflectance of these chalcopyrite nanotip arrays has been characterized by UV-vis spectrophotometer and the efficient light-trapping effect has been observed. Large scale (∼4′′) and high density (1010 tips/cm2) of chalcopyrite nanotip arrays have been obtained by using low ion energy (< 1 kV), short processing duration (< 30 min), and template-free. Besides, orientation and length of these chalcopyrite nanotip arrays are controllable. Our results can be the guide for other nanostructured materials fabrication by ion sputtering and are available for industrial production as well.

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U2 - 10.1021/am501161j

DO - 10.1021/am501161j

M3 - Article

AN - SCOPUS:84902438579

SN - 1944-8244

VL - 6

SP - 8327

EP - 8336

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 11

ER -

Large scale and orientation-controllable nanotip structures on CuInS ₂, Cu(In,Ga)S₂, CuInSe₂, and Cu(In,Ga)Se ₂ by low energy ion beam bombardment process: Growth and characterization

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