Abstract
Laser frequency-modulated (FM) spectroscopy has been used as an axial probe of a laser-guided electric discharge in sodium-argon vapor contained in an optically accessible metal heat pipe oven. Absorption measurements in the region 23 106-23 881 cm-1 provided accurate line positions (±<0.006 cm-1) for 141 transitions in the ν′ = 3-8 ← ν″ = 0 and ν′ = 5-9 ← ν″ = 1 bands of NaH (Α1Σ+ - Χ1Σ+). In addition, 18 transitions of Na (3p to 9-13d and 11-14s) and 10 of argon (5p-4s) were measured. Analysis of the spectrum indicates that perhaps all absorption signals are due to neutrals NaH, Na, and Ar and are observed via "population" modulation.
Original language | English |
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Pages (from-to) | 222-229 |
Number of pages | 8 |
Journal | Journal of molecular spectroscopy |
Volume | 186 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1997 Dec |
All Science Journal Classification (ASJC) codes
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry