Linear adsorption of nonionic organic compounds from water onto hydrophilic minerals: Silica and alumina

Yu Hong Su, Yong Guan Zhu, Guangyao Sheng, Cary T. Chiou

Research output: Contribution to journalArticlepeer-review

51 Citations (Scopus)

Abstract

To characterize the linear adsorption phenomena in aqueous nonionic organic solute-mineral systems, the adsorption isotherms of some low-molecular- weightnonpolar nonionic solutes (1,2,3-trichlorobenzene, lindane, phenanthrene, and pyrene) and polar nonionic solutes (1,3-dinitrobenzene and 2,4-dinitrotoluene) from single-and binary-solute solutions on hydrophilic silica and alumina were established. Toward this objective, the influences of temperature, ionic strength, and pH on adsorption were also determined. It is found that linear adsorption exhibits low exothermic heats and practically no adsorptive competition. The solute-solid configuration and the adsorptive force consistent with these effects were hypothesized. For nonpolar solutes, the adsorption occurs presumably by London (dispersion) forces onto a water film above the mineral surface. For polar solutes, the adsorption is also assisted by polar-group interactions. The reduced adsorptive forces of solutes with hydrophilic minerals due to physical separation by the water film and the low fractions of the water-film surface covered by solutes offer a theoretical basis for linear solute adsorption, low exothermic heats, and no adsorptive competition. The postulated adsorptive forces are supported by observations that ionic strength or pH poses no effect on the adsorption of nonpolar solutes while it exhibits a significant effect on the uptake of polar solutes.

Original languageEnglish
Pages (from-to)6949-6954
Number of pages6
JournalEnvironmental Science and Technology
Volume40
Issue number22
DOIs
Publication statusPublished - 2006 Nov 15

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry

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