Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery

Shu Chi Wu; Zhengxun Lai; Ruoting Dong; Shin Yi Tang; Kuangye Wang; Tzu Yi Yang; Ying Chun Shen; Hsiang Ju Liao; Teng Yu Su; Chiou Ru Cheng; Yuanfei Ai; Yu Ze Chen; Yi Chung Wang; Ling Lee; Yi Jen Yu; Johnny C. Ho; Yu Lun Chueh

doi:10.1016/j.nanoen.2023.108273

Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery

Shu Chi Wu, Zhengxun Lai, Ruoting Dong, Shin Yi Tang, Kuangye Wang, Tzu Yi Yang, Ying Chun Shen, Hsiang Ju Liao, Teng Yu Su, Chiou Ru Cheng, Yuanfei Ai, Yu Ze Chen, Yi Chung Wang, Ling Lee, Yi Jen Yu, Johnny C. Ho, Yu Lun Chueh

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Recent advances in the use of organic-inorganic hybrid perovskites have been investigated in a variety of applications, such as solar cells, photodetectors, light-emitting devices, and lasers, because of their outstanding semiconductor properties. Furthermore, the perovskite structure can host extrinsic elements, making it a promising candidate for battery applications. Previous studies have shown that organic-inorganic hybrid perovskites can be suitable anode materials for both lithium- and sodium-ion batteries. However, multivalent rechargeable batteries with perovskite materials have not yet been realized. Herein, we studied the electrochemical performance of three-dimensional (CH₃NH₃PbI₃ (MAPbI₃) and long-chain alkylammonium (C₄H₉NH₃)₂(CH₃NH₃)₃Pb₄I₁₃ ((iBA)₂(MA)₃Pb₄I₁₃) thin films as electrode materials for rechargeable Al-ion batteries. Our results showed that (iBA)₂(MA)₃Pb₄I₁₃ presented a specific capacity of 257 mAh g^–1 at a current density of 0.1 A g⁻¹ and delivered 108 mAh g^–1 after 250 cycles at a current density of 0.3 A g⁻¹ with a retention of as high as 91 %, demonstrating a crucial role of isobutyl amine (C₄H₉NH₃) due to the unique hydrogen-bonding interaction of isobutyl amine that hinders the shuttle effect of polyiodide. The results open a new direction for the use of organic–inorganic hybrid perovskites for new secondary aluminum ion batteries.

Original language	English
Article number	108273
Journal	Nano Energy
Volume	110
DOIs	https://doi.org/10.1016/j.nanoen.2023.108273
Publication status	Published - 2023 Jun 1

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
General Materials Science
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.nanoen.2023.108273

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Wu, S. C., Lai, Z., Dong, R., Tang, S. Y., Wang, K., Yang, T. Y., Shen, Y. C., Liao, H. J., Su, T. Y., Cheng, C. R., Ai, Y., Chen, Y. Z., Wang, Y. C., Lee, L., Yu, Y. J., Ho, J. C., & Chueh, Y. L. (2023). Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery. Nano Energy, 110, Article 108273. https://doi.org/10.1016/j.nanoen.2023.108273

@article{2761c7e2289448658ba8b1e79e1b3d47,

title = "Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery",

abstract = "Recent advances in the use of organic-inorganic hybrid perovskites have been investigated in a variety of applications, such as solar cells, photodetectors, light-emitting devices, and lasers, because of their outstanding semiconductor properties. Furthermore, the perovskite structure can host extrinsic elements, making it a promising candidate for battery applications. Previous studies have shown that organic-inorganic hybrid perovskites can be suitable anode materials for both lithium- and sodium-ion batteries. However, multivalent rechargeable batteries with perovskite materials have not yet been realized. Herein, we studied the electrochemical performance of three-dimensional (CH3NH3PbI3 (MAPbI3) and long-chain alkylammonium (C4H9NH3)2(CH3NH3)3Pb4I13 ((iBA)2(MA)3Pb4I13) thin films as electrode materials for rechargeable Al-ion batteries. Our results showed that (iBA)2(MA)3Pb4I13 presented a specific capacity of 257 mAh g–1 at a current density of 0.1 A g−1 and delivered 108 mAh g–1 after 250 cycles at a current density of 0.3 A g−1 with a retention of as high as 91 \%, demonstrating a crucial role of isobutyl amine (C4H9NH3) due to the unique hydrogen-bonding interaction of isobutyl amine that hinders the shuttle effect of polyiodide. The results open a new direction for the use of organic–inorganic hybrid perovskites for new secondary aluminum ion batteries.",

author = "Wu, \{Shu Chi\} and Zhengxun Lai and Ruoting Dong and Tang, \{Shin Yi\} and Kuangye Wang and Yang, \{Tzu Yi\} and Shen, \{Ying Chun\} and Liao, \{Hsiang Ju\} and Su, \{Teng Yu\} and Cheng, \{Chiou Ru\} and Yuanfei Ai and Chen, \{Yu Ze\} and Wang, \{Yi Chung\} and Ling Lee and Yu, \{Yi Jen\} and Ho, \{Johnny C.\} and Chueh, \{Yu Lun\}",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

month = jun,

day = "1",

doi = "10.1016/j.nanoen.2023.108273",

language = "English",

volume = "110",

journal = "Nano Energy",

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T1 - Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery

AU - Wu, Shu Chi

AU - Lai, Zhengxun

AU - Dong, Ruoting

AU - Tang, Shin Yi

AU - Wang, Kuangye

AU - Yang, Tzu Yi

AU - Shen, Ying Chun

AU - Liao, Hsiang Ju

AU - Su, Teng Yu

AU - Cheng, Chiou Ru

AU - Ai, Yuanfei

AU - Chen, Yu Ze

AU - Wang, Yi Chung

AU - Lee, Ling

AU - Yu, Yi Jen

AU - Ho, Johnny C.

AU - Chueh, Yu Lun

PY - 2023/6/1

Y1 - 2023/6/1

N2 - Recent advances in the use of organic-inorganic hybrid perovskites have been investigated in a variety of applications, such as solar cells, photodetectors, light-emitting devices, and lasers, because of their outstanding semiconductor properties. Furthermore, the perovskite structure can host extrinsic elements, making it a promising candidate for battery applications. Previous studies have shown that organic-inorganic hybrid perovskites can be suitable anode materials for both lithium- and sodium-ion batteries. However, multivalent rechargeable batteries with perovskite materials have not yet been realized. Herein, we studied the electrochemical performance of three-dimensional (CH3NH3PbI3 (MAPbI3) and long-chain alkylammonium (C4H9NH3)2(CH3NH3)3Pb4I13 ((iBA)2(MA)3Pb4I13) thin films as electrode materials for rechargeable Al-ion batteries. Our results showed that (iBA)2(MA)3Pb4I13 presented a specific capacity of 257 mAh g–1 at a current density of 0.1 A g−1 and delivered 108 mAh g–1 after 250 cycles at a current density of 0.3 A g−1 with a retention of as high as 91 %, demonstrating a crucial role of isobutyl amine (C4H9NH3) due to the unique hydrogen-bonding interaction of isobutyl amine that hinders the shuttle effect of polyiodide. The results open a new direction for the use of organic–inorganic hybrid perovskites for new secondary aluminum ion batteries.

AB - Recent advances in the use of organic-inorganic hybrid perovskites have been investigated in a variety of applications, such as solar cells, photodetectors, light-emitting devices, and lasers, because of their outstanding semiconductor properties. Furthermore, the perovskite structure can host extrinsic elements, making it a promising candidate for battery applications. Previous studies have shown that organic-inorganic hybrid perovskites can be suitable anode materials for both lithium- and sodium-ion batteries. However, multivalent rechargeable batteries with perovskite materials have not yet been realized. Herein, we studied the electrochemical performance of three-dimensional (CH3NH3PbI3 (MAPbI3) and long-chain alkylammonium (C4H9NH3)2(CH3NH3)3Pb4I13 ((iBA)2(MA)3Pb4I13) thin films as electrode materials for rechargeable Al-ion batteries. Our results showed that (iBA)2(MA)3Pb4I13 presented a specific capacity of 257 mAh g–1 at a current density of 0.1 A g−1 and delivered 108 mAh g–1 after 250 cycles at a current density of 0.3 A g−1 with a retention of as high as 91 %, demonstrating a crucial role of isobutyl amine (C4H9NH3) due to the unique hydrogen-bonding interaction of isobutyl amine that hinders the shuttle effect of polyiodide. The results open a new direction for the use of organic–inorganic hybrid perovskites for new secondary aluminum ion batteries.

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DO - 10.1016/j.nanoen.2023.108273

M3 - Article

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SN - 2211-2855

VL - 110

JO - Nano Energy

JF - Nano Energy

M1 - 108273

ER -

Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery

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