Manganese(III) acetate initiated oxidative free radical reaction between benzoylindoles and dimethyl malonate

Sheow Fong Wang; Che Ping Chuang

doi:10.3987/com-96-7687

Manganese(III) acetate initiated oxidative free radical reaction between benzoylindoles and dimethyl malonate

Sheow Fong Wang, Che Ping Chuang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A free radical reaction between benzoylindoles and dimethyl malonate initiated by manganese(III) acetate is described. This free radical reaction provides a new method for the synthesis of indolo[1,2-b]isoquinolines and benzo[b]carbazoles. With meta substituent on benzoyl group, this reaction shows unusual high regioselectivity.

Original language	English
Pages (from-to)	347-359
Number of pages	13
Journal	Heterocycles
Volume	45
Issue number	2
DOIs	https://doi.org/10.3987/com-96-7687
Publication status	Published - 1997

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Pharmacology
Organic Chemistry

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abstract = "A free radical reaction between benzoylindoles and dimethyl malonate initiated by manganese(III) acetate is described. This free radical reaction provides a new method for the synthesis of indolo[1,2-b]isoquinolines and benzo[b]carbazoles. With meta substituent on benzoyl group, this reaction shows unusual high regioselectivity.",

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AB - A free radical reaction between benzoylindoles and dimethyl malonate initiated by manganese(III) acetate is described. This free radical reaction provides a new method for the synthesis of indolo[1,2-b]isoquinolines and benzo[b]carbazoles. With meta substituent on benzoyl group, this reaction shows unusual high regioselectivity.

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