Abstract
Mass-analyzed threshold ionization (MATI) spectroscopy is applied for the first time to a metal van der Waals complex, AlAr. The experimental configuration for MATI uses a time-of-flight mass spectrometer, oriented perpendicular to the molecular beam axis, without modification of any components. The vibrationally resolved spectrum yields a frequency of ω″e=67 cm-1 for the ground state of Al+Ar, and a value of ΔG″ 1 2=39 cm-1 for neutral AlAr.
Original language | English |
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Pages (from-to) | 156-160 |
Number of pages | 5 |
Journal | Chemical Physics Letters |
Volume | 211 |
Issue number | 1 |
DOIs | |
Publication status | Published - 1993 Aug 6 |
All Science Journal Classification (ASJC) codes
- General Physics and Astronomy
- Physical and Theoretical Chemistry