Mechanical properties of ultra-thin HfO2 films studied by nano scratches tests

Wei En Fu, Yong Qing Chang, Chia Wei Chang, Chih Kai Yao, Jiunn-Der Liao

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

10-nm-thick atomic layer deposited HfO2 films were characterized in terms of wear resistance and indentation hardness to investigate the thermal annealing induced impacts on mechanical properties. The wear resistance of ultra-thin films at low loads was characterized using nano-scratch tests with an atomic force microscope. The depth of the nano-scratches decreases with increasing annealing temperature, indicating that the hardness of the annealed films increases with the annealing temperatures. Surface nanoindentation was also performed to confirm the nanoscratch test results. The hardness variation of the annealed films is due to the generation of HfSixOy induced by the thermal annealing. X-ray photoelectron spectroscopy measurements proved that the hardness of formed HfSixOy with increasing annealing temperatures. The existence of HfSixOy broadens the interface, and causes the increase of the interfacial layer thickness. As a result, the surface hardness increases with the increasing HfSi xOy induced by the thermal annealing.

Original languageEnglish
Pages (from-to)402-406
Number of pages5
JournalThin Solid Films
Volume529
DOIs
Publication statusPublished - 2013 Feb 1

Fingerprint

Ultrathin films
mechanical properties
Annealing
hardness
Mechanical properties
Hardness
annealing
thin films
wear resistance
Wear resistance
Nanoindentation
nanoindentation
indentation
Indentation
Temperature
temperature
Loads (forces)
Microscopes
X ray photoelectron spectroscopy
microscopes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Fu, Wei En ; Chang, Yong Qing ; Chang, Chia Wei ; Yao, Chih Kai ; Liao, Jiunn-Der. / Mechanical properties of ultra-thin HfO2 films studied by nano scratches tests. In: Thin Solid Films. 2013 ; Vol. 529. pp. 402-406.
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Mechanical properties of ultra-thin HfO2 films studied by nano scratches tests. / Fu, Wei En; Chang, Yong Qing; Chang, Chia Wei; Yao, Chih Kai; Liao, Jiunn-Der.

In: Thin Solid Films, Vol. 529, 01.02.2013, p. 402-406.

Research output: Contribution to journalArticle

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AU - Yao, Chih Kai

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AB - 10-nm-thick atomic layer deposited HfO2 films were characterized in terms of wear resistance and indentation hardness to investigate the thermal annealing induced impacts on mechanical properties. The wear resistance of ultra-thin films at low loads was characterized using nano-scratch tests with an atomic force microscope. The depth of the nano-scratches decreases with increasing annealing temperature, indicating that the hardness of the annealed films increases with the annealing temperatures. Surface nanoindentation was also performed to confirm the nanoscratch test results. The hardness variation of the annealed films is due to the generation of HfSixOy induced by the thermal annealing. X-ray photoelectron spectroscopy measurements proved that the hardness of formed HfSixOy with increasing annealing temperatures. The existence of HfSixOy broadens the interface, and causes the increase of the interfacial layer thickness. As a result, the surface hardness increases with the increasing HfSi xOy induced by the thermal annealing.

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