Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode

Chien Wen Wang, Kung Wen Liu, Wei Fu Chen, Jing De Zhou, Hong Ping Lin, Chun Han Hsu, Ping Lin Kuo

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Mesoporous SiO2/C hollow spheres have been successfully synthesized via a one-step template process and carbonization of a mesoporous SiO2/poly(ethylene oxide)/phenolic formaldehyde resin hollow nanocomposite, and then evaluated as anode materials for lithium-ion batteries. The continuous carbon framework significantly led the SiO2/C hollow spheres to reach a high conductivity (3.9 × 10-4 S cm-1) compared with the SiO2 hollow spheres (<10-9 S cm-1), furthermore, the unique hollow nanostructure with a large volume interior and numerous mesopores plugged with carbon in the silica shell, could accommodate the volume variation and improve the structural strain for Li ion conduction, as well as allow rapid access of Li ions during charge-discharge cycling. For battery applications, at 100 mA g-1 charge/discharge rates, the reversible capacity of this mesoporous SiO2/C anode (624 mA h g-1) is over ten times higher than that of the SiO2 anode (61 mA h g-1). More specifically, even under the high discharge rate of 3000 mA g-1, this SiO2/C hollow nanostructure exhibits a specific capacity of 582 mA h g-1, featuring a high retention of more than 90% of its low discharge rate of 100 mA g-1. This demonstrates that the effective conduction of electrons through the continuous carbon network and the fast transport of Li ions through the nanoscale SiO2 shell significantly contribute to the high-rate performance.

Original languageEnglish
Pages (from-to)1398-1405
Number of pages8
JournalInorganic Chemistry Frontiers
Volume3
Issue number11
DOIs
Publication statusPublished - 2016 Nov

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Anodes
Carbon
Ions
Nanostructures
Carbonization
Polyethylene oxides
Silicon Dioxide
Formaldehyde
Nanocomposites
Resins
Electrons
Lithium-ion batteries

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

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title = "Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode",
abstract = "Mesoporous SiO2/C hollow spheres have been successfully synthesized via a one-step template process and carbonization of a mesoporous SiO2/poly(ethylene oxide)/phenolic formaldehyde resin hollow nanocomposite, and then evaluated as anode materials for lithium-ion batteries. The continuous carbon framework significantly led the SiO2/C hollow spheres to reach a high conductivity (3.9 × 10-4 S cm-1) compared with the SiO2 hollow spheres (<10-9 S cm-1), furthermore, the unique hollow nanostructure with a large volume interior and numerous mesopores plugged with carbon in the silica shell, could accommodate the volume variation and improve the structural strain for Li ion conduction, as well as allow rapid access of Li ions during charge-discharge cycling. For battery applications, at 100 mA g-1 charge/discharge rates, the reversible capacity of this mesoporous SiO2/C anode (624 mA h g-1) is over ten times higher than that of the SiO2 anode (61 mA h g-1). More specifically, even under the high discharge rate of 3000 mA g-1, this SiO2/C hollow nanostructure exhibits a specific capacity of 582 mA h g-1, featuring a high retention of more than 90{\%} of its low discharge rate of 100 mA g-1. This demonstrates that the effective conduction of electrons through the continuous carbon network and the fast transport of Li ions through the nanoscale SiO2 shell significantly contribute to the high-rate performance.",
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Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode. / Wang, Chien Wen; Liu, Kung Wen; Chen, Wei Fu; Zhou, Jing De; Lin, Hong Ping; Hsu, Chun Han; Kuo, Ping Lin.

In: Inorganic Chemistry Frontiers, Vol. 3, No. 11, 11.2016, p. 1398-1405.

Research output: Contribution to journalArticle

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T1 - Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode

AU - Wang, Chien Wen

AU - Liu, Kung Wen

AU - Chen, Wei Fu

AU - Zhou, Jing De

AU - Lin, Hong Ping

AU - Hsu, Chun Han

AU - Kuo, Ping Lin

PY - 2016/11

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AB - Mesoporous SiO2/C hollow spheres have been successfully synthesized via a one-step template process and carbonization of a mesoporous SiO2/poly(ethylene oxide)/phenolic formaldehyde resin hollow nanocomposite, and then evaluated as anode materials for lithium-ion batteries. The continuous carbon framework significantly led the SiO2/C hollow spheres to reach a high conductivity (3.9 × 10-4 S cm-1) compared with the SiO2 hollow spheres (<10-9 S cm-1), furthermore, the unique hollow nanostructure with a large volume interior and numerous mesopores plugged with carbon in the silica shell, could accommodate the volume variation and improve the structural strain for Li ion conduction, as well as allow rapid access of Li ions during charge-discharge cycling. For battery applications, at 100 mA g-1 charge/discharge rates, the reversible capacity of this mesoporous SiO2/C anode (624 mA h g-1) is over ten times higher than that of the SiO2 anode (61 mA h g-1). More specifically, even under the high discharge rate of 3000 mA g-1, this SiO2/C hollow nanostructure exhibits a specific capacity of 582 mA h g-1, featuring a high retention of more than 90% of its low discharge rate of 100 mA g-1. This demonstrates that the effective conduction of electrons through the continuous carbon network and the fast transport of Li ions through the nanoscale SiO2 shell significantly contribute to the high-rate performance.

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