MISCIBLE BLENDS OF A VINYLIDENE CHLORIDE/VINYL CHLORIDE COPOLYMER WITH POLYMETHACRYLATES.

Eamor Woo, J. W. Barlow, D. R. Paul

Research output: Chapter in Book/Report/Conference proceedingConference contribution

32 Citations (Scopus)

Abstract

A copolymer of vinylidene chloride and vinyl chloride containing 13. 5% of the latter has been found to form completely miscible blends with atactic and isotactic poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), and poly(cyclohexyl methacrylate). All but the latter of these blends were shown to exhibit lower critical solution temperature behavior at temperatures below that at which the copolymer rapidly degrades. The copolymer was found to be only partially miscible with poly(isopropyl methacrylate), while no detectable level of miscibility was observed with poly(methyl acrylate), poly(ethyl acrylate), poly(vinyl acetate, poly(vinyl methyl ether), or poly(vinyl methyl ketone). Information about interactions between components in the miscible blends was estimated from melting point data and is discussed.

Original languageEnglish
Title of host publicationJournal of Polymer Science, Polymer Symposia
EditorsA.G. Pinkus
Pages137-150
Number of pages14
Edition71
Publication statusPublished - 1984

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Copolymers
Ketones
Polymethyl methacrylates
Melting point
Ethers
Solubility
Temperature

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Woo, E., Barlow, J. W., & Paul, D. R. (1984). MISCIBLE BLENDS OF A VINYLIDENE CHLORIDE/VINYL CHLORIDE COPOLYMER WITH POLYMETHACRYLATES. In A. G. Pinkus (Ed.), Journal of Polymer Science, Polymer Symposia (71 ed., pp. 137-150)
Woo, Eamor ; Barlow, J. W. ; Paul, D. R. / MISCIBLE BLENDS OF A VINYLIDENE CHLORIDE/VINYL CHLORIDE COPOLYMER WITH POLYMETHACRYLATES. Journal of Polymer Science, Polymer Symposia. editor / A.G. Pinkus. 71. ed. 1984. pp. 137-150
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abstract = "A copolymer of vinylidene chloride and vinyl chloride containing 13. 5{\%} of the latter has been found to form completely miscible blends with atactic and isotactic poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), and poly(cyclohexyl methacrylate). All but the latter of these blends were shown to exhibit lower critical solution temperature behavior at temperatures below that at which the copolymer rapidly degrades. The copolymer was found to be only partially miscible with poly(isopropyl methacrylate), while no detectable level of miscibility was observed with poly(methyl acrylate), poly(ethyl acrylate), poly(vinyl acetate, poly(vinyl methyl ether), or poly(vinyl methyl ketone). Information about interactions between components in the miscible blends was estimated from melting point data and is discussed.",
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Woo, E, Barlow, JW & Paul, DR 1984, MISCIBLE BLENDS OF A VINYLIDENE CHLORIDE/VINYL CHLORIDE COPOLYMER WITH POLYMETHACRYLATES. in AG Pinkus (ed.), Journal of Polymer Science, Polymer Symposia. 71 edn, pp. 137-150.

MISCIBLE BLENDS OF A VINYLIDENE CHLORIDE/VINYL CHLORIDE COPOLYMER WITH POLYMETHACRYLATES. / Woo, Eamor; Barlow, J. W.; Paul, D. R.

Journal of Polymer Science, Polymer Symposia. ed. / A.G. Pinkus. 71. ed. 1984. p. 137-150.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - A copolymer of vinylidene chloride and vinyl chloride containing 13. 5% of the latter has been found to form completely miscible blends with atactic and isotactic poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), and poly(cyclohexyl methacrylate). All but the latter of these blends were shown to exhibit lower critical solution temperature behavior at temperatures below that at which the copolymer rapidly degrades. The copolymer was found to be only partially miscible with poly(isopropyl methacrylate), while no detectable level of miscibility was observed with poly(methyl acrylate), poly(ethyl acrylate), poly(vinyl acetate, poly(vinyl methyl ether), or poly(vinyl methyl ketone). Information about interactions between components in the miscible blends was estimated from melting point data and is discussed.

AB - A copolymer of vinylidene chloride and vinyl chloride containing 13. 5% of the latter has been found to form completely miscible blends with atactic and isotactic poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), and poly(cyclohexyl methacrylate). All but the latter of these blends were shown to exhibit lower critical solution temperature behavior at temperatures below that at which the copolymer rapidly degrades. The copolymer was found to be only partially miscible with poly(isopropyl methacrylate), while no detectable level of miscibility was observed with poly(methyl acrylate), poly(ethyl acrylate), poly(vinyl acetate, poly(vinyl methyl ether), or poly(vinyl methyl ketone). Information about interactions between components in the miscible blends was estimated from melting point data and is discussed.

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Woo E, Barlow JW, Paul DR. MISCIBLE BLENDS OF A VINYLIDENE CHLORIDE/VINYL CHLORIDE COPOLYMER WITH POLYMETHACRYLATES. In Pinkus AG, editor, Journal of Polymer Science, Polymer Symposia. 71 ed. 1984. p. 137-150