Mixed cation thiocyanate-based pseudohalide perovskite solar cells with high efficiency and stability

Yu Hsien Chiang, Ming Hsien Li, Hsin Min Cheng, Po Shen Shen, Peter Chen

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Novel organic-inorganic hybrid perovskite compounds composed of mixed A-site cation (Formamidinium and Cesium) and pseudohalides (SCN and I) ions are successfully synthesized. These new classes of hybrid perovskites photovoltaics exhibited remarkable power conversion efficiency of more than 16% with excellent stability against moisture in ambient environment and under low-light storage condition. The existence of SCN- ion inclusion is confirmed by secondary ion mass spectrometry and Fourier transform infrared spectroscopy. The SCN--doped pseudohalide is advantageous for the formation of large perovskite grains, as well as the performance and stability of the device. (Graph Presented).

Original languageEnglish
Pages (from-to)2403-2409
Number of pages7
JournalACS Applied Materials and Interfaces
Volume9
Issue number3
DOIs
Publication statusPublished - 2017 Jan 25

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this