Moderately concentrated electrolyte improves solid–electrolyte interphase and sodium storage performance of hard carbon

Patra Jagabandhu, Hao Tzu Huang, Weijiang Xue, Chao Wang, Ahmed S. Helal, Ju Li, Jeng Kuei Chang

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Hard carbon (HC) is a promising anode for sodium-ion batteries. The current hurdles for the HC electrodes are insufficient coulombic efficiency (CE), rate capability, and cyclic stability. This study reveals that an intelligent electrolyte design can effectively overcome these limitations. The sodium salt, concentration, and solvent of the electrolytes are systematically investigated. Incorporation of ethylene carbonate (EC) in propylene carbonate (PC) electrolyte can promote the formation of contact ion pairs and ion aggregates between Na+ and FSI. At a moderate concentration, the 3 mol dm−3 NaFSI in PC:EC electrolyte with reasonable conductivity and viscosity can lead to the formation of a robust organic–inorganic balanced solid–electrolyte interphase, which is thoroughly examined by electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. With this, the first-cycle and steady-state CE of the HC electrode is increased to 85% and>99.9%, respectively, and the reversible sodiation/desodiation capacities at high rates are markedly improved. In addition, 95% of the initial capacity can be retained after 500 charge–discharge cycles. The proposed electrolyte represents a huge step towards HC electrodes with high effectiveness and durability for electrochemical Na+ storage.

Original languageEnglish
Pages (from-to)146-154
Number of pages9
JournalEnergy Storage Materials
Volume16
DOIs
Publication statusPublished - 2019 Jan 1

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Electrolytes
Carbon
Sodium
Carbonates
Ions
Electrodes
Propylene
Ethylene
Electrochemical impedance spectroscopy
Anodes
Durability
X ray photoelectron spectroscopy
Salts
Viscosity
Transmission electron microscopy
ethylene carbonate
propylene carbonate

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)
  • Energy Engineering and Power Technology

Cite this

Jagabandhu, Patra ; Huang, Hao Tzu ; Xue, Weijiang ; Wang, Chao ; Helal, Ahmed S. ; Li, Ju ; Chang, Jeng Kuei. / Moderately concentrated electrolyte improves solid–electrolyte interphase and sodium storage performance of hard carbon. In: Energy Storage Materials. 2019 ; Vol. 16. pp. 146-154.
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Moderately concentrated electrolyte improves solid–electrolyte interphase and sodium storage performance of hard carbon. / Jagabandhu, Patra; Huang, Hao Tzu; Xue, Weijiang; Wang, Chao; Helal, Ahmed S.; Li, Ju; Chang, Jeng Kuei.

In: Energy Storage Materials, Vol. 16, 01.01.2019, p. 146-154.

Research output: Contribution to journalArticle

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AU - Li, Ju

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N2 - Hard carbon (HC) is a promising anode for sodium-ion batteries. The current hurdles for the HC electrodes are insufficient coulombic efficiency (CE), rate capability, and cyclic stability. This study reveals that an intelligent electrolyte design can effectively overcome these limitations. The sodium salt, concentration, and solvent of the electrolytes are systematically investigated. Incorporation of ethylene carbonate (EC) in propylene carbonate (PC) electrolyte can promote the formation of contact ion pairs and ion aggregates between Na+ and FSI–. At a moderate concentration, the 3 mol dm−3 NaFSI in PC:EC electrolyte with reasonable conductivity and viscosity can lead to the formation of a robust organic–inorganic balanced solid–electrolyte interphase, which is thoroughly examined by electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. With this, the first-cycle and steady-state CE of the HC electrode is increased to 85% and>99.9%, respectively, and the reversible sodiation/desodiation capacities at high rates are markedly improved. In addition, 95% of the initial capacity can be retained after 500 charge–discharge cycles. The proposed electrolyte represents a huge step towards HC electrodes with high effectiveness and durability for electrochemical Na+ storage.

AB - Hard carbon (HC) is a promising anode for sodium-ion batteries. The current hurdles for the HC electrodes are insufficient coulombic efficiency (CE), rate capability, and cyclic stability. This study reveals that an intelligent electrolyte design can effectively overcome these limitations. The sodium salt, concentration, and solvent of the electrolytes are systematically investigated. Incorporation of ethylene carbonate (EC) in propylene carbonate (PC) electrolyte can promote the formation of contact ion pairs and ion aggregates between Na+ and FSI–. At a moderate concentration, the 3 mol dm−3 NaFSI in PC:EC electrolyte with reasonable conductivity and viscosity can lead to the formation of a robust organic–inorganic balanced solid–electrolyte interphase, which is thoroughly examined by electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. With this, the first-cycle and steady-state CE of the HC electrode is increased to 85% and>99.9%, respectively, and the reversible sodiation/desodiation capacities at high rates are markedly improved. In addition, 95% of the initial capacity can be retained after 500 charge–discharge cycles. The proposed electrolyte represents a huge step towards HC electrodes with high effectiveness and durability for electrochemical Na+ storage.

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