Nano-tip emission of tetrahedral amorphous carbon

Ming Chi Kan, Jow Lay Huang, James C. Sung, Kuei Hsien Chen, Ding Fwu Lii

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)


Various forms of tetrahedral amorphous carbon were deposited on n-type silicon (100) substrate. Tetrahedral amorphous carbon is an excellent electron emitter for field emission array (FEA) applications. The negative electron affinity (NEA) of diamond surface was believed to facilitate the electron emission for diamond-like carbon. However, in this research, we have demonstrated that the geometric enhancement factor may be even more effective to promote electron emission. Moreover, we have succeeded in depositing high-density (4×1010 emitters/cm2) of nano-sized emitters. The electrons are emitted under both the effect of enhanced field due to the sharp tips, and the optimized distortion of tetrahedral bonding of carbon atoms. The sp3/(sp3+sp2) ratio of C-C bonded tetrahedral amorphous carbon films was measured by ESCA and Raman; and the geometry of emitters by AFM. The lowest turn on applied field strength of 4.6 V/μm was found at the current density of 10 μA/cm2. High reproducibility of field emission was also observed in this study.

Original languageEnglish
Pages (from-to)1691-1697
Number of pages7
JournalDiamond and Related Materials
Issue number10-11
Publication statusPublished - 2003

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Chemistry(all)
  • Mechanical Engineering
  • Materials Chemistry
  • Electrical and Electronic Engineering


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