Nanoimprinting of Flexible Polycarbonate Sheets with a Flexible Polymer Mold and Application to Superhydrophobic Surfaces

Chia Ching Liang, Chun-Hung Lin, Tsung Chieh Cheng, Jiann Shieh, Hsi Ho Lin

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

This study demonstrates a reliable process for the direct nanoimprinting of a flexible polycarbonate (PC) sheet using a perfluoropolyether (PFPE) mold. PC is a commonly used flexible substrate with optical transparency, low thermal expansion coefficient, high mechanical strength, and excellent deformation resistivity. The imprint performances of PFPE, hard/soft-polydimethylsiloxane, and silicon molds are compared. Given that the heating temperature is near the glass transition temperature (≈153 °C) of PC, only PFPE mold can be fully patterned into PC substrate with viable integrity. The mechanical property and gas permeability of the materials are investigated to determine the mechanism of the flexible PFPE mold, which performs better than a rigid silicon mold. Nanoimprint process using a PFPE mold is performed at 153 °C and 5 bars. The lower imprint temperature or imprint pressure of the proposed process compared with those from previous studies is favorable in nanoimprinting. Finally, nanoroughness-on-nanopillar hierarchical surfaces, which possess superhydrophobic slippery characteristics superior to those of nanoroughness-only surfaces, are obtained by treating PC nanopillar arrays imprinted by PFPE mold with C 4 F 8 plasma.

Original languageEnglish
Article number1500030
JournalAdvanced Materials Interfaces
Volume2
Issue number7
DOIs
Publication statusPublished - 2015 May 1

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Polycarbonates
Polymers
Silicon
Gas permeability
Molds
Substrates
Polydimethylsiloxane
Transparency
Strength of materials
Thermal expansion
Plasmas
Heating
Mechanical properties
Temperature

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering

Cite this

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abstract = "This study demonstrates a reliable process for the direct nanoimprinting of a flexible polycarbonate (PC) sheet using a perfluoropolyether (PFPE) mold. PC is a commonly used flexible substrate with optical transparency, low thermal expansion coefficient, high mechanical strength, and excellent deformation resistivity. The imprint performances of PFPE, hard/soft-polydimethylsiloxane, and silicon molds are compared. Given that the heating temperature is near the glass transition temperature (≈153 °C) of PC, only PFPE mold can be fully patterned into PC substrate with viable integrity. The mechanical property and gas permeability of the materials are investigated to determine the mechanism of the flexible PFPE mold, which performs better than a rigid silicon mold. Nanoimprint process using a PFPE mold is performed at 153 °C and 5 bars. The lower imprint temperature or imprint pressure of the proposed process compared with those from previous studies is favorable in nanoimprinting. Finally, nanoroughness-on-nanopillar hierarchical surfaces, which possess superhydrophobic slippery characteristics superior to those of nanoroughness-only surfaces, are obtained by treating PC nanopillar arrays imprinted by PFPE mold with C 4 F 8 plasma.",
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Nanoimprinting of Flexible Polycarbonate Sheets with a Flexible Polymer Mold and Application to Superhydrophobic Surfaces. / Liang, Chia Ching; Lin, Chun-Hung; Cheng, Tsung Chieh; Shieh, Jiann; Lin, Hsi Ho.

In: Advanced Materials Interfaces, Vol. 2, No. 7, 1500030, 01.05.2015.

Research output: Contribution to journalArticle

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