Nanostructured LiCoO2 cathode by hydrothermal process

Kuan Zong Fung, Chung Ta Ni, Su Yi Tsai, Mei Han Chen, A. F. Orliukas, Gunars Bajars

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A high performance Li-ion thin film battery is essential for nano/microelectronics that require micro power source. Thus, the cathode of thin film battery needs to be prepared using an adequate thin film technology. In this study, the main objective was to fabricate a nanosize LiCoO2 film as the cathode of the Li-ion thin film battery. The hydrothermal process was adopted for the thin film deposition of LiCoO2. The solutions were prepared from the lithium nitrate and cobalt acetate in deionized water. LiCoO2 thin film was precipitated on a substrate during hydrothermal process and followed by annealing at desired temperatures up to 4h in air. The crystallization of LiCoO2 film was analyzed by DTA/TG and XRD. A well crystallized hexagonal LiCoO2 and cubic CO3O4 film were obtained. The surface morphology of as deposited LiCoO2 film was examined by SEM. Finally, CV test and charge/discharge tests were conducted on an assembled Li battery using the deposited LiCoO2 film by hydrothermal process.

Original languageEnglish
Title of host publicationCeramic Materials for Energy Applications IV
Subtitle of host publicationCeramic Engineering and Science Proceedings
EditorsHua-Tay Lin, Yutai Katoh, Josef Matyas
PublisherAmerican Ceramic Society
Pages23-34
Number of pages12
Edition7
ISBN (Electronic)9781119031185, 9781119040200, 9781119040262, 9781119040279, 9781119040286, 9781119040385, 9781119040439
Publication statusPublished - 2014 Jan 1
EventCeramic Materials for Energy Applications IV - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014 - Daytona Beach, United States
Duration: 2014 Jan 262014 Jan 31

Publication series

NameCeramic Engineering and Science Proceedings
Number7
Volume35
ISSN (Print)0196-6219

Other

OtherCeramic Materials for Energy Applications IV - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014
CountryUnited States
CityDaytona Beach
Period14-01-2614-01-31

Fingerprint

Cathodes
Thin films
Ions
Deionized water
Crystallization
Lithium
Microelectronics
Differential thermal analysis
Surface morphology
Nitrates
Cobalt
Acetates
Annealing
Scanning electron microscopy
Substrates
Air
Temperature

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Fung, K. Z., Ni, C. T., Tsai, S. Y., Chen, M. H., Orliukas, A. F., & Bajars, G. (2014). Nanostructured LiCoO2 cathode by hydrothermal process. In H-T. Lin, Y. Katoh, & J. Matyas (Eds.), Ceramic Materials for Energy Applications IV: Ceramic Engineering and Science Proceedings (7 ed., pp. 23-34). (Ceramic Engineering and Science Proceedings; Vol. 35, No. 7). American Ceramic Society.
Fung, Kuan Zong ; Ni, Chung Ta ; Tsai, Su Yi ; Chen, Mei Han ; Orliukas, A. F. ; Bajars, Gunars. / Nanostructured LiCoO2 cathode by hydrothermal process. Ceramic Materials for Energy Applications IV: Ceramic Engineering and Science Proceedings. editor / Hua-Tay Lin ; Yutai Katoh ; Josef Matyas. 7. ed. American Ceramic Society, 2014. pp. 23-34 (Ceramic Engineering and Science Proceedings; 7).
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Fung, KZ, Ni, CT, Tsai, SY, Chen, MH, Orliukas, AF & Bajars, G 2014, Nanostructured LiCoO2 cathode by hydrothermal process. in H-T Lin, Y Katoh & J Matyas (eds), Ceramic Materials for Energy Applications IV: Ceramic Engineering and Science Proceedings. 7 edn, Ceramic Engineering and Science Proceedings, no. 7, vol. 35, American Ceramic Society, pp. 23-34, Ceramic Materials for Energy Applications IV - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014, Daytona Beach, United States, 14-01-26.

Nanostructured LiCoO2 cathode by hydrothermal process. / Fung, Kuan Zong; Ni, Chung Ta; Tsai, Su Yi; Chen, Mei Han; Orliukas, A. F.; Bajars, Gunars.

Ceramic Materials for Energy Applications IV: Ceramic Engineering and Science Proceedings. ed. / Hua-Tay Lin; Yutai Katoh; Josef Matyas. 7. ed. American Ceramic Society, 2014. p. 23-34 (Ceramic Engineering and Science Proceedings; Vol. 35, No. 7).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - A high performance Li-ion thin film battery is essential for nano/microelectronics that require micro power source. Thus, the cathode of thin film battery needs to be prepared using an adequate thin film technology. In this study, the main objective was to fabricate a nanosize LiCoO2 film as the cathode of the Li-ion thin film battery. The hydrothermal process was adopted for the thin film deposition of LiCoO2. The solutions were prepared from the lithium nitrate and cobalt acetate in deionized water. LiCoO2 thin film was precipitated on a substrate during hydrothermal process and followed by annealing at desired temperatures up to 4h in air. The crystallization of LiCoO2 film was analyzed by DTA/TG and XRD. A well crystallized hexagonal LiCoO2 and cubic CO3O4 film were obtained. The surface morphology of as deposited LiCoO2 film was examined by SEM. Finally, CV test and charge/discharge tests were conducted on an assembled Li battery using the deposited LiCoO2 film by hydrothermal process.

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Fung KZ, Ni CT, Tsai SY, Chen MH, Orliukas AF, Bajars G. Nanostructured LiCoO2 cathode by hydrothermal process. In Lin H-T, Katoh Y, Matyas J, editors, Ceramic Materials for Energy Applications IV: Ceramic Engineering and Science Proceedings. 7 ed. American Ceramic Society. 2014. p. 23-34. (Ceramic Engineering and Science Proceedings; 7).