One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge: Synthesis, characterization and molecular properties

Abhijit Pal; Merry Mitra; Bhaskar Biswas; Siang Hua Huang; Hui Lien Tsai; Rajarshi Ghosh

One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge: Synthesis, characterization and molecular properties

Abhijit Pal, Merry Mitra, Bhaskar Biswas, Siang Hua Huang, Hui Lien Tsai, Rajarshi Ghosh

Department of Chemistry

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1 Citation (Scopus)

Abstract

A one dimensional (1D) coordination polymer [Cd(bzpy)(NCS)(SCN)] _n (1) is synthesized and X-ray crystallo-graphically characterized. 1 crystallizes in P-1 space group and the asymmetric unit contains one crystallographically independent cadmium(II) centre, one ligand (bzpy) and four thiocyanate ions. Cadmium(I) is surrounded by one nitrogen and one oxygen atom from the benzoyl pyridine moiety. Cadmium(I) here lies in a distorted octahedral environment with the CdN₃S₂0 chromophore. Thermogravimetry reveals that 1 is thermally stable up to about 130 °C. After excitation at 350 nm, it gives strong emission in dimethylformamide (DMF) at 417 nm with a hump at 545 nm due to π-π^* transition.

Original language	English
Pages (from-to)	801-805
Number of pages	5
Journal	Journal of the Indian Chemical Society
Volume	90
Issue number	6
Publication status	Published - 2013 Jun

All Science Journal Classification (ASJC) codes

Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Electrochemistry

Cite this

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title = "One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge: Synthesis, characterization and molecular properties",

abstract = "A one dimensional (1D) coordination polymer [Cd(bzpy)(NCS)(SCN)] n (1) is synthesized and X-ray crystallo-graphically characterized. 1 crystallizes in P-1 space group and the asymmetric unit contains one crystallographically independent cadmium(II) centre, one ligand (bzpy) and four thiocyanate ions. Cadmium(I) is surrounded by one nitrogen and one oxygen atom from the benzoyl pyridine moiety. Cadmium(I) here lies in a distorted octahedral environment with the CdN3S20 chromophore. Thermogravimetry reveals that 1 is thermally stable up to about 130 °C. After excitation at 350 nm, it gives strong emission in dimethylformamide (DMF) at 417 nm with a hump at 545 nm due to π-π* transition.",

author = "Abhijit Pal and Merry Mitra and Bhaskar Biswas and Huang, {Siang Hua} and Tsai, {Hui Lien} and Rajarshi Ghosh",

year = "2013",

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language = "English",

volume = "90",

pages = "801--805",

journal = "Journal of the Indian Chemical Society",

issn = "0019-4522",

publisher = "Indian Chemical Society",

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TY - JOUR

T1 - One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge

T2 - Synthesis, characterization and molecular properties

AU - Pal, Abhijit

AU - Mitra, Merry

AU - Biswas, Bhaskar

AU - Huang, Siang Hua

AU - Tsai, Hui Lien

AU - Ghosh, Rajarshi

PY - 2013/6

Y1 - 2013/6

N2 - A one dimensional (1D) coordination polymer [Cd(bzpy)(NCS)(SCN)] n (1) is synthesized and X-ray crystallo-graphically characterized. 1 crystallizes in P-1 space group and the asymmetric unit contains one crystallographically independent cadmium(II) centre, one ligand (bzpy) and four thiocyanate ions. Cadmium(I) is surrounded by one nitrogen and one oxygen atom from the benzoyl pyridine moiety. Cadmium(I) here lies in a distorted octahedral environment with the CdN3S20 chromophore. Thermogravimetry reveals that 1 is thermally stable up to about 130 °C. After excitation at 350 nm, it gives strong emission in dimethylformamide (DMF) at 417 nm with a hump at 545 nm due to π-π* transition.

AB - A one dimensional (1D) coordination polymer [Cd(bzpy)(NCS)(SCN)] n (1) is synthesized and X-ray crystallo-graphically characterized. 1 crystallizes in P-1 space group and the asymmetric unit contains one crystallographically independent cadmium(II) centre, one ligand (bzpy) and four thiocyanate ions. Cadmium(I) is surrounded by one nitrogen and one oxygen atom from the benzoyl pyridine moiety. Cadmium(I) here lies in a distorted octahedral environment with the CdN3S20 chromophore. Thermogravimetry reveals that 1 is thermally stable up to about 130 °C. After excitation at 350 nm, it gives strong emission in dimethylformamide (DMF) at 417 nm with a hump at 545 nm due to π-π* transition.

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M3 - Article

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SN - 0019-4522

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JO - Journal of the Indian Chemical Society

JF - Journal of the Indian Chemical Society

IS - 6

ER -

One dimensional coordination polymer of cadmiym(II) with thiocyanate bridge: Synthesis, characterization and molecular properties

Abstract

All Science Journal Classification (ASJC) codes

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