Optimization of small molecule organic solar cells based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 )

Jhong Ciao Ke, Yeong-Her Wang, Chien Jung Huang, Pao Hsun Huang, Chih Chieh Kang

Research output: Contribution to conferencePaper

Abstract

The small molecule organic solar cell based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) was fabricated. The structure of device is indium tin oxide (ITO)/SubPc (3∼21 nm)/C 60 (30 nm)/2, 9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP) (10 nm)/silver (Ag). The thickness of SubPc in device is varied from 3nm to 21nm to get the optimal thickness for the better performance. The maximum power conversion efficiency of 1.47% was obtained in the device at the SubPc thickness of 9 nm under 100 mW/cm 2 AM1.5G illumination. The best performance of device at 9 nm SubPc layer is attributed to reach the optimal balance between the light absorption efficiency and the carrier collection efficiency in the device. In addition, the open-circuit voltage (Voc) maximum value of device is associated with the energy difference between the highest occupied molecular orbital (HOMO) of the donor and the lowest unoccupied molecular orbital (LUMO) of the acceptor, and the Voc of device is determined by difference of work function of electrodes. In order to increase the Voc of device, the Molybdenum Oxide (MoO 3 ) layer was inserted between the ITO and the SubPc layer, resulting in the enhancement of Voc from 0.46V to 1V. As a result, the efficiency of device increased from 1.47% to 2.52%.

Original languageEnglish
Pages47-49
Number of pages3
Publication statusPublished - 2014 Jan 1
Event2nd International Conference on Innovation, Communication and Engineering, ICICE 2013 - Qingdao, China
Duration: 2013 Oct 262013 Nov 1

Other

Other2nd International Conference on Innovation, Communication and Engineering, ICICE 2013
CountryChina
CityQingdao
Period13-10-2613-11-01

Fingerprint

Fullerenes
Boron
Molecular orbitals
Tin oxides
Indium
Molecules
Molybdenum oxide
Open circuit voltage
Light absorption
Conversion efficiency
Silver
Lighting
Electrodes
Organic solar cells

All Science Journal Classification (ASJC) codes

  • Management of Technology and Innovation

Cite this

Ke, J. C., Wang, Y-H., Huang, C. J., Huang, P. H., & Kang, C. C. (2014). Optimization of small molecule organic solar cells based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) . 47-49. Paper presented at 2nd International Conference on Innovation, Communication and Engineering, ICICE 2013, Qingdao, China.
Ke, Jhong Ciao ; Wang, Yeong-Her ; Huang, Chien Jung ; Huang, Pao Hsun ; Kang, Chih Chieh. / Optimization of small molecule organic solar cells based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) Paper presented at 2nd International Conference on Innovation, Communication and Engineering, ICICE 2013, Qingdao, China.3 p.
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abstract = "The small molecule organic solar cell based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) was fabricated. The structure of device is indium tin oxide (ITO)/SubPc (3∼21 nm)/C 60 (30 nm)/2, 9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP) (10 nm)/silver (Ag). The thickness of SubPc in device is varied from 3nm to 21nm to get the optimal thickness for the better performance. The maximum power conversion efficiency of 1.47{\%} was obtained in the device at the SubPc thickness of 9 nm under 100 mW/cm 2 AM1.5G illumination. The best performance of device at 9 nm SubPc layer is attributed to reach the optimal balance between the light absorption efficiency and the carrier collection efficiency in the device. In addition, the open-circuit voltage (Voc) maximum value of device is associated with the energy difference between the highest occupied molecular orbital (HOMO) of the donor and the lowest unoccupied molecular orbital (LUMO) of the acceptor, and the Voc of device is determined by difference of work function of electrodes. In order to increase the Voc of device, the Molybdenum Oxide (MoO 3 ) layer was inserted between the ITO and the SubPc layer, resulting in the enhancement of Voc from 0.46V to 1V. As a result, the efficiency of device increased from 1.47{\%} to 2.52{\%}.",
author = "Ke, {Jhong Ciao} and Yeong-Her Wang and Huang, {Chien Jung} and Huang, {Pao Hsun} and Kang, {Chih Chieh}",
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Ke, JC, Wang, Y-H, Huang, CJ, Huang, PH & Kang, CC 2014, ' Optimization of small molecule organic solar cells based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) ' Paper presented at 2nd International Conference on Innovation, Communication and Engineering, ICICE 2013, Qingdao, China, 13-10-26 - 13-11-01, pp. 47-49.

Optimization of small molecule organic solar cells based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) . / Ke, Jhong Ciao; Wang, Yeong-Her; Huang, Chien Jung; Huang, Pao Hsun; Kang, Chih Chieh.

2014. 47-49 Paper presented at 2nd International Conference on Innovation, Communication and Engineering, ICICE 2013, Qingdao, China.

Research output: Contribution to conferencePaper

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AU - Ke, Jhong Ciao

AU - Wang, Yeong-Her

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AU - Huang, Pao Hsun

AU - Kang, Chih Chieh

PY - 2014/1/1

Y1 - 2014/1/1

N2 - The small molecule organic solar cell based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) was fabricated. The structure of device is indium tin oxide (ITO)/SubPc (3∼21 nm)/C 60 (30 nm)/2, 9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP) (10 nm)/silver (Ag). The thickness of SubPc in device is varied from 3nm to 21nm to get the optimal thickness for the better performance. The maximum power conversion efficiency of 1.47% was obtained in the device at the SubPc thickness of 9 nm under 100 mW/cm 2 AM1.5G illumination. The best performance of device at 9 nm SubPc layer is attributed to reach the optimal balance between the light absorption efficiency and the carrier collection efficiency in the device. In addition, the open-circuit voltage (Voc) maximum value of device is associated with the energy difference between the highest occupied molecular orbital (HOMO) of the donor and the lowest unoccupied molecular orbital (LUMO) of the acceptor, and the Voc of device is determined by difference of work function of electrodes. In order to increase the Voc of device, the Molybdenum Oxide (MoO 3 ) layer was inserted between the ITO and the SubPc layer, resulting in the enhancement of Voc from 0.46V to 1V. As a result, the efficiency of device increased from 1.47% to 2.52%.

AB - The small molecule organic solar cell based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) was fabricated. The structure of device is indium tin oxide (ITO)/SubPc (3∼21 nm)/C 60 (30 nm)/2, 9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP) (10 nm)/silver (Ag). The thickness of SubPc in device is varied from 3nm to 21nm to get the optimal thickness for the better performance. The maximum power conversion efficiency of 1.47% was obtained in the device at the SubPc thickness of 9 nm under 100 mW/cm 2 AM1.5G illumination. The best performance of device at 9 nm SubPc layer is attributed to reach the optimal balance between the light absorption efficiency and the carrier collection efficiency in the device. In addition, the open-circuit voltage (Voc) maximum value of device is associated with the energy difference between the highest occupied molecular orbital (HOMO) of the donor and the lowest unoccupied molecular orbital (LUMO) of the acceptor, and the Voc of device is determined by difference of work function of electrodes. In order to increase the Voc of device, the Molybdenum Oxide (MoO 3 ) layer was inserted between the ITO and the SubPc layer, resulting in the enhancement of Voc from 0.46V to 1V. As a result, the efficiency of device increased from 1.47% to 2.52%.

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Ke JC, Wang Y-H, Huang CJ, Huang PH, Kang CC. Optimization of small molecule organic solar cells based on Boron Subphthalocyanine Chloride (SubPc) and fullerene (C 60 ) . 2014. Paper presented at 2nd International Conference on Innovation, Communication and Engineering, ICICE 2013, Qingdao, China.