Oxidative free radical reactions of enamino esters

Che Ping Chuang, Yi Lung Wu

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

Oxidative free radical reactions of enamino esters are described. Electrophilic carbon-centered radicals produced by the cerium(IV) ammonium nitrate (CAN) oxidation of β-dicarbonyl compounds undergo efficient addition to the C-C double bond of enamino esters. This CAN mediated free radical reaction between enamino esters and β-dicarbonyl compounds provides a novel method for the synthesis of highly substituted pyrroles. The direct CAN oxidation of β-enaminocinnamates gave the dimerization products effectively.

Original languageEnglish
Pages (from-to)1841-1847
Number of pages7
JournalTetrahedron
Volume60
Issue number8
DOIs
Publication statusPublished - 2004 Feb 16

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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