Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

Bo Jhih Lin; Wei Hsin Chen; Tzu Hsien Hsieh; Hwai Chyuan Ong; Pau Loke Show; Salman Raza Naqvi

doi:10.1016/j.renene.2018.12.111

Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

Bo Jhih Lin, Wei Hsin Chen, Tzu Hsien Hsieh, Hwai Chyuan Ong, Pau Loke Show, Salman Raza Naqvi

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

Original language	English
Pages (from-to)	223-234
Number of pages	12
Journal	Renewable Energy
Volume	136
DOIs	https://doi.org/10.1016/j.renene.2018.12.111
Publication status	Published - 2019 Jun

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment

Access to Document

10.1016/j.renene.2018.12.111

Fingerprint Dive into the research topics of 'Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels'. Together they form a unique fingerprint.

Cite this

@article{f760894c9133426aad468a46bf065848,

title = "Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels",

abstract = "Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.",

author = "Lin, {Bo Jhih} and Chen, {Wei Hsin} and Hsieh, {Tzu Hsien} and Ong, {Hwai Chyuan} and Show, {Pau Loke} and Naqvi, {Salman Raza}",

note = "Funding Information: The authors gratefully acknowledge the financial support of the Ministry of Science and Technology, Taiwan , R.O.C., under the grant number MOST 106-2923-E-006-002-MY3 for this research. ",

year = "2019",

month = jun,

doi = "10.1016/j.renene.2018.12.111",

language = "English",

volume = "136",

pages = "223--234",

journal = "Renewable Energy",

issn = "0960-1481",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

AU - Lin, Bo Jhih

AU - Chen, Wei Hsin

AU - Hsieh, Tzu Hsien

AU - Ong, Hwai Chyuan

AU - Show, Pau Loke

AU - Naqvi, Salman Raza

N1 - Funding Information: The authors gratefully acknowledge the financial support of the Ministry of Science and Technology, Taiwan , R.O.C., under the grant number MOST 106-2923-E-006-002-MY3 for this research.

PY - 2019/6

Y1 - 2019/6

N2 - Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

AB - Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

UR - http://www.scopus.com/inward/record.url?scp=85061607286&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85061607286&partnerID=8YFLogxK

U2 - 10.1016/j.renene.2018.12.111

DO - 10.1016/j.renene.2018.12.111

M3 - Article

AN - SCOPUS:85061607286

VL - 136

SP - 223

EP - 234

JO - Renewable Energy

JF - Renewable Energy

SN - 0960-1481

ER -