Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

Bo Jhih Lin; Wei Hsin Chen; Tzu Hsien Hsieh; Hwai Chyuan Ong; Pau Loke Show; Salman Raza Naqvi

doi:10.1016/j.renene.2018.12.111

Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

Bo Jhih Lin, Wei Hsin Chen, Tzu Hsien Hsieh, Hwai Chyuan Ong, Pau Loke Show, Salman Raza Naqvi

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

Original language	English
Pages (from-to)	223-234
Number of pages	12
Journal	Renewable Energy
Volume	136
DOIs	https://doi.org/10.1016/j.renene.2018.12.111
Publication status	Published - 2019 Jun

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.renene.2018.12.111

Cite this

@article{f760894c9133426aad468a46bf065848,

title = "Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels",

abstract = "Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.",

author = "Lin, {Bo Jhih} and Chen, {Wei Hsin} and Hsieh, {Tzu Hsien} and Ong, {Hwai Chyuan} and Show, {Pau Loke} and Naqvi, {Salman Raza}",

note = "Funding Information: The authors gratefully acknowledge the financial support of the Ministry of Science and Technology, Taiwan , R.O.C., under the grant number MOST 106-2923-E-006-002-MY3 for this research. ",

year = "2019",

month = jun,

doi = "10.1016/j.renene.2018.12.111",

language = "English",

volume = "136",

pages = "223--234",

journal = "Renewable Energy",

issn = "0960-1481",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

AU - Lin, Bo Jhih

AU - Chen, Wei Hsin

AU - Hsieh, Tzu Hsien

AU - Ong, Hwai Chyuan

AU - Show, Pau Loke

AU - Naqvi, Salman Raza

N1 - Funding Information: The authors gratefully acknowledge the financial support of the Ministry of Science and Technology, Taiwan , R.O.C., under the grant number MOST 106-2923-E-006-002-MY3 for this research.

PY - 2019/6

Y1 - 2019/6

N2 - Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

AB - Emulsification is an economic route for the applications of pyrolysis bio-oil in diesel engines and industrial furnaces and heating. The oxidative reaction interaction of a number of bio-oil/diesel emulsified fuels at various bio-oil contents and bio-oil-to-emulsifier weight ratios (i.e. B/E ratios) is analyzed to provide a basis for the applications of pyrolysis bio-oil. The commercial Atlox 4914 is used as the surfactant, while a thermogravimetric analyzer is employed in the analysis. The interaction phenomena are obviously observed during the oxidative reaction of the emulsified fuels. The interaction can be partitioned into a weak antagonistic zone (≤210 °C) and a significant synergistic zone (≥210 °C). In the synergistic zone, the oxidation of the fuels is enhanced and the maximum interaction occurs at about 380 °C. A dimensionless parameter termed the synergistic index (SI) is introduced to measure the interaction degree. An increase in the bio-oil content intensifies the interaction up to around 11%, whereas increasing the B/E ratio lowers the SI value. Meanwhile, an opposite trend in the fuel reactivity and burnout temperature is exhibited. The obtained results are able to provide a strategy for the preparation of bio-oil/diesel emulsified fuels to intensify their fuel reactivity and applications in industry.

UR - http://www.scopus.com/inward/record.url?scp=85061607286&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85061607286&partnerID=8YFLogxK

U2 - 10.1016/j.renene.2018.12.111

DO - 10.1016/j.renene.2018.12.111

M3 - Article

AN - SCOPUS:85061607286

VL - 136

SP - 223

EP - 234

JO - Renewable Energy

JF - Renewable Energy

SN - 0960-1481

ER -

Oxidative reaction interaction and synergistic index of emulsified pyrolysis bio-oil/diesel fuels

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this