Oxide mediated liquid-solid growth of high aspect ratio aligned gold silicide nanowires on Si(110) substrates

Umananda M. Bhatta, Ashutosh Rath, Jatis K. Dash, Jay Ghatak, Lai Yi-Feng, Chuan-Pu Liu, P. V. Satyam

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Silicon nanowires grown using the vapor-liquid-solid method are promising candidates for nanoelectronics applications. The nanowires grow from an Au-Si catalyst during silicon chemical vapor deposition. In this paper, the effect of temperature, oxide at the interface and substrate orientation on the nucleation and growth kinetics during formation of nanogold silicide structures is explained using an oxide mediated liquid-solid growth mechanism. Using real time insitu high temperature transmission electron microscopy (with 40ms time resolution), we show the formation of high aspect ratio (≈15.0) aligned gold silicide nanorods in the presence of native oxide at the interface during insitu annealing of gold thin films on Si(110) substrates. Steps observed in the growth rate and real time electron diffraction show the existence of liquid Au-Si nano-alloy structures on the surface besides the un-reacted gold nanostructures. These results might enable us to engineer the growth of nanowires and similar structures with an Au-Si alloy as a catalyst.

Original languageEnglish
Article number465601
JournalNanotechnology
Volume20
Issue number46
DOIs
Publication statusPublished - 2009 Nov 6

Fingerprint

Gold
Oxides
Nanowires
Aspect ratio
Silicon
Liquids
Substrates
Catalysts
Nanoelectronics
Growth kinetics
Nanorods
Electron diffraction
Chemical vapor deposition
Nanostructures
Nucleation
Vapors
Annealing
Transmission electron microscopy
Engineers
Thin films

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

Cite this

Bhatta, Umananda M. ; Rath, Ashutosh ; Dash, Jatis K. ; Ghatak, Jay ; Yi-Feng, Lai ; Liu, Chuan-Pu ; Satyam, P. V. / Oxide mediated liquid-solid growth of high aspect ratio aligned gold silicide nanowires on Si(110) substrates. In: Nanotechnology. 2009 ; Vol. 20, No. 46.
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Oxide mediated liquid-solid growth of high aspect ratio aligned gold silicide nanowires on Si(110) substrates. / Bhatta, Umananda M.; Rath, Ashutosh; Dash, Jatis K.; Ghatak, Jay; Yi-Feng, Lai; Liu, Chuan-Pu; Satyam, P. V.

In: Nanotechnology, Vol. 20, No. 46, 465601, 06.11.2009.

Research output: Contribution to journalArticle

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AU - Bhatta, Umananda M.

AU - Rath, Ashutosh

AU - Dash, Jatis K.

AU - Ghatak, Jay

AU - Yi-Feng, Lai

AU - Liu, Chuan-Pu

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