Perovskite-based solar cells with inorganic inverted hybrid planar heterojunction structure

Wei Chih Lai; Kun Wei Lin; Tzung Fang Guo; Peter Chen; Yuan Yu Liao

doi:10.1063/1.5010951

Perovskite-based solar cells with inorganic inverted hybrid planar heterojunction structure

Wei Chih Lai, Kun Wei Lin, Tzung Fang Guo, Peter Chen, Yuan Yu Liao

Department of Photonics

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

We demonstrated the good performance of inorganic inverted CH₃NH₃PbI₃ perovskite-based solar cells (SCs) with glass/ITO/NiO_x/CH₃NH₃PbI₃ perovskite/C₆₀/ room temperature (RT)-sputtered ZnO/Al structure. We adopted spin coating and RT sputtering for the deposition of NiO_x and ZnO, respectively. The inorganic hole and electron transport layer of NiO_x and RT-sputtered ZnO, respectively, could improve the open-circuit voltage (V_OC), short-circuit current density (J_SC), and power conversion efficiency (η%) of the SCs. We obtained inorganic inverted CH₃NH₃PbI₃ perovskite-based SCs with a J_SC of 21.96 A/cm², a V_OC of 1.02 V, a fill factor (FF%) of 68.2%, and an η% of 15.3% despite the sputtering damage of the RT-sputtered ZnO deposition. Moreover, the RT-sputtered ZnO could function as a diffusion barrier for Al, moisture, and O₂. The inorganic inverted CH₃NH₃PbI₃ perovskite-based SCs demonstrated improved storage reliability.

Original language	English
Article number	015109
Journal	AIP Advances
Volume	8
Issue number	1
DOIs	https://doi.org/10.1063/1.5010951
Publication status	Published - 2018 Jan 1

All Science Journal Classification (ASJC) codes

General Physics and Astronomy

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10.1063/1.5010951

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@article{e92e38c6526f4cf0b1dd72717a877354,

title = "Perovskite-based solar cells with inorganic inverted hybrid planar heterojunction structure",

abstract = "We demonstrated the good performance of inorganic inverted CH3NH3PbI3 perovskite-based solar cells (SCs) with glass/ITO/NiOx/CH3NH3PbI3 perovskite/C60/ room temperature (RT)-sputtered ZnO/Al structure. We adopted spin coating and RT sputtering for the deposition of NiOx and ZnO, respectively. The inorganic hole and electron transport layer of NiOx and RT-sputtered ZnO, respectively, could improve the open-circuit voltage (VOC), short-circuit current density (JSC), and power conversion efficiency (η%) of the SCs. We obtained inorganic inverted CH3NH3PbI3 perovskite-based SCs with a JSC of 21.96 A/cm2, a VOC of 1.02 V, a fill factor (FF%) of 68.2%, and an η% of 15.3% despite the sputtering damage of the RT-sputtered ZnO deposition. Moreover, the RT-sputtered ZnO could function as a diffusion barrier for Al, moisture, and O2. The inorganic inverted CH3NH3PbI3 perovskite-based SCs demonstrated improved storage reliability.",

author = "Lai, {Wei Chih} and Lin, {Kun Wei} and Guo, {Tzung Fang} and Peter Chen and Liao, {Yuan Yu}",

note = "Funding Information: The author Lai is grateful to the Ministry of Science and Technology (MOST) of Taiwan for its financial support under Contract Nos. MOST 104-2221-E-006-069-MY3, NSC 101-2221-E-006-066-MY3, and NSC102-3113-P-009-007-CC2. The author Guo would like to thank MOST of Taiwan (MOST 102-2682-M-006-001-MY3 and MOST 103-2119-M-006-020) and the Asian Office of Aerospace Research and Development (AOARD-14-4012) for financially supporting this research This research was also made possible through the support of the Advanced Optoelectronic Technology Center, the National Cheng Kung University (as a project of the Ministry of Education of Taiwan), and the Bureau of Energy, Ministry of Economic Affairs of Taiwan, under Contract No. 102-E0603. Publisher Copyright: {\textcopyright} 2018 Author(s).",

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doi = "10.1063/1.5010951",

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T1 - Perovskite-based solar cells with inorganic inverted hybrid planar heterojunction structure

AU - Lai, Wei Chih

AU - Lin, Kun Wei

AU - Guo, Tzung Fang

AU - Chen, Peter

AU - Liao, Yuan Yu

N1 - Funding Information: The author Lai is grateful to the Ministry of Science and Technology (MOST) of Taiwan for its financial support under Contract Nos. MOST 104-2221-E-006-069-MY3, NSC 101-2221-E-006-066-MY3, and NSC102-3113-P-009-007-CC2. The author Guo would like to thank MOST of Taiwan (MOST 102-2682-M-006-001-MY3 and MOST 103-2119-M-006-020) and the Asian Office of Aerospace Research and Development (AOARD-14-4012) for financially supporting this research This research was also made possible through the support of the Advanced Optoelectronic Technology Center, the National Cheng Kung University (as a project of the Ministry of Education of Taiwan), and the Bureau of Energy, Ministry of Economic Affairs of Taiwan, under Contract No. 102-E0603. Publisher Copyright: © 2018 Author(s).

PY - 2018/1/1

Y1 - 2018/1/1

N2 - We demonstrated the good performance of inorganic inverted CH3NH3PbI3 perovskite-based solar cells (SCs) with glass/ITO/NiOx/CH3NH3PbI3 perovskite/C60/ room temperature (RT)-sputtered ZnO/Al structure. We adopted spin coating and RT sputtering for the deposition of NiOx and ZnO, respectively. The inorganic hole and electron transport layer of NiOx and RT-sputtered ZnO, respectively, could improve the open-circuit voltage (VOC), short-circuit current density (JSC), and power conversion efficiency (η%) of the SCs. We obtained inorganic inverted CH3NH3PbI3 perovskite-based SCs with a JSC of 21.96 A/cm2, a VOC of 1.02 V, a fill factor (FF%) of 68.2%, and an η% of 15.3% despite the sputtering damage of the RT-sputtered ZnO deposition. Moreover, the RT-sputtered ZnO could function as a diffusion barrier for Al, moisture, and O2. The inorganic inverted CH3NH3PbI3 perovskite-based SCs demonstrated improved storage reliability.

AB - We demonstrated the good performance of inorganic inverted CH3NH3PbI3 perovskite-based solar cells (SCs) with glass/ITO/NiOx/CH3NH3PbI3 perovskite/C60/ room temperature (RT)-sputtered ZnO/Al structure. We adopted spin coating and RT sputtering for the deposition of NiOx and ZnO, respectively. The inorganic hole and electron transport layer of NiOx and RT-sputtered ZnO, respectively, could improve the open-circuit voltage (VOC), short-circuit current density (JSC), and power conversion efficiency (η%) of the SCs. We obtained inorganic inverted CH3NH3PbI3 perovskite-based SCs with a JSC of 21.96 A/cm2, a VOC of 1.02 V, a fill factor (FF%) of 68.2%, and an η% of 15.3% despite the sputtering damage of the RT-sputtered ZnO deposition. Moreover, the RT-sputtered ZnO could function as a diffusion barrier for Al, moisture, and O2. The inorganic inverted CH3NH3PbI3 perovskite-based SCs demonstrated improved storage reliability.

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M1 - 015109

ER -

Perovskite-based solar cells with inorganic inverted hybrid planar heterojunction structure

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