pH Dependence of Interparticle Coupling for Gold Nanoparticle Assemblies Formation: Electrostatic Attraction and Hydrogen Bonding

Chia Hao Su, Pei Lin Wu, Chen-Sheng Yeh

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

With the addition of ω-sulfanylalkanoic or ω -alkyldisulfanylalkanoic acids to sodium-contained aqueous Au colloidal solutions, close-packed self-assembly occurred UV-vis, TEM, solid-state 13C NMR, and FT-IR spectra were employed to study the resulting aggregation arrays. The resulting two-dimensional Au assemblies exhibited interparticle coupling via both hydrogen bonding and electrostatic interactions at pH 6. Either acidic (pH 3) or base (pH 11) generated significant three-dimensional close-packed aggregates. It is suggested that electrostatic interactions might lead to the aggregates during the dry-up process in the preparation of TEM samples of the Au nanoparticles capped with COO- terminals at pH 11. For the acidic solutions (pH 3), coagulation was governed by hydrogen-bonding forces.

Original languageEnglish
Pages (from-to)189-193
Number of pages5
JournalBulletin of the Chemical Society of Japan
Volume77
Issue number1
DOIs
Publication statusPublished - 2004 Jan 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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