Phase evolution of solid-state BaTiO3 powder prepared with the ultrafine BaCO3 and TiO2

Ting Tai Lee, Chi-Yuen Huang, Che Yuan Chang, I. Kuan Cheng, Ching Li Hu, Chun Te Lee, Masayuki Fujimoto

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The phase evolution, nucleation, and sintered ceramics of barium titanate (BaTiO3, BT) powder prepared by solid-state synthesis with an ultrafine starting material (27 m2/g of BaCO3 and 190 m2/g of TiO2) were investigated in this study. Surface diffusion between BaCO3 and TiO2 was observed at a relatively low temperature of 400 °C by transmission electron microscopy. Rapid nucleation of the BT and cubic BT phases was observed at 500 °C by x-ray diffraction. The derivative thermogravimetry curve clearly shows a single step of BT formation at 600 °C. In short, pure BT particles with an average particle size of 250 nm and high tetragonality were prepared by solid-state synthesis, which produced X7R ceramics with high dielectric permittivity, high insulation resistance, and a clear core-shell structure.

Original languageEnglish
Pages (from-to)2495-2502
Number of pages8
JournalJournal of Materials Research
Volume27
Issue number19
DOIs
Publication statusPublished - 2012 Oct 14

Fingerprint

Powders
Nucleation
nucleation
ceramics
solid state
Barium titanate
Surface diffusion
synthesis
surface diffusion
thermogravimetry
insulation
barium
Thermogravimetric analysis
Insulation
x ray diffraction
Permittivity
Diffraction
Particle size
permittivity
Transmission electron microscopy

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Lee, Ting Tai ; Huang, Chi-Yuen ; Chang, Che Yuan ; Cheng, I. Kuan ; Hu, Ching Li ; Lee, Chun Te ; Fujimoto, Masayuki. / Phase evolution of solid-state BaTiO3 powder prepared with the ultrafine BaCO3 and TiO2 In: Journal of Materials Research. 2012 ; Vol. 27, No. 19. pp. 2495-2502.
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abstract = "The phase evolution, nucleation, and sintered ceramics of barium titanate (BaTiO3, BT) powder prepared by solid-state synthesis with an ultrafine starting material (27 m2/g of BaCO3 and 190 m2/g of TiO2) were investigated in this study. Surface diffusion between BaCO3 and TiO2 was observed at a relatively low temperature of 400 °C by transmission electron microscopy. Rapid nucleation of the BT and cubic BT phases was observed at 500 °C by x-ray diffraction. The derivative thermogravimetry curve clearly shows a single step of BT formation at 600 °C. In short, pure BT particles with an average particle size of 250 nm and high tetragonality were prepared by solid-state synthesis, which produced X7R ceramics with high dielectric permittivity, high insulation resistance, and a clear core-shell structure.",
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Phase evolution of solid-state BaTiO3 powder prepared with the ultrafine BaCO3 and TiO2 . / Lee, Ting Tai; Huang, Chi-Yuen; Chang, Che Yuan; Cheng, I. Kuan; Hu, Ching Li; Lee, Chun Te; Fujimoto, Masayuki.

In: Journal of Materials Research, Vol. 27, No. 19, 14.10.2012, p. 2495-2502.

Research output: Contribution to journalArticle

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AU - Lee, Ting Tai

AU - Huang, Chi-Yuen

AU - Chang, Che Yuan

AU - Cheng, I. Kuan

AU - Hu, Ching Li

AU - Lee, Chun Te

AU - Fujimoto, Masayuki

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AB - The phase evolution, nucleation, and sintered ceramics of barium titanate (BaTiO3, BT) powder prepared by solid-state synthesis with an ultrafine starting material (27 m2/g of BaCO3 and 190 m2/g of TiO2) were investigated in this study. Surface diffusion between BaCO3 and TiO2 was observed at a relatively low temperature of 400 °C by transmission electron microscopy. Rapid nucleation of the BT and cubic BT phases was observed at 500 °C by x-ray diffraction. The derivative thermogravimetry curve clearly shows a single step of BT formation at 600 °C. In short, pure BT particles with an average particle size of 250 nm and high tetragonality were prepared by solid-state synthesis, which produced X7R ceramics with high dielectric permittivity, high insulation resistance, and a clear core-shell structure.

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