Photodissociation spectroscopy of the Mg+-CO2 complex and its isotopic analogs

C. S. Yeh, K. F. Willey, D. L. Robbins, J. S. Pilgrim, M. A. Duncan

Research output: Contribution to journalArticlepeer-review

80 Citations (Scopus)

Abstract

Mg+-CO2 ion-molecule cluster complexes are produced by laser vaporization in a pulsed nozzle cluster source. The vibronic spectroscopy in these complexes is studied with mass-selected photodissociation spectroscopy in a reflectron time-of-flight mass spectrometer. Two excited electronic states are observed (2) 2Σ+ and 2Π. The 2Π state has a vibrational progression in the metal-CO2 stretching mode (ω′e=381.8 cm-1). The complexes are linear (Mg+-OCO) and are bound by the charge-quadrupole interaction. The dissociation energy (D″ 0) is 14.7 kcal/mol. Corresponding spectra are measured for each of the 24, 25, and 26 isotopes of magnesium. These results are compared to theoretical predictions made by Bauschlicher and co-workers.

Original languageEnglish
Pages (from-to)1867-1875
Number of pages9
JournalThe Journal of Chemical Physics
Volume98
Issue number3
DOIs
Publication statusPublished - 1993 Jan 1

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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