Photodissociative charge transfer in Ag+-pyridine complex

Yuh Sheng Yang, Chen Sheng Yeh

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

Ag+-pyridine complex has been generated in the gas phase. Dissociative metal-to-ligand charge transfer was observed through the photodissociation technique. Two continuum absorption/dissociation bands were recorded by monitoring the pyridine cation fragments as a function of the laser wavelengths and the possible dissociative mechanisms are discussed. The binding energy of the Ag+-pyridine was determined to be 45 kcal/mol. Ag+ bonding to nitrogen atom in C5H5N with ion-dipole interactions is suggested.

Original languageEnglish
Pages (from-to)395-400
Number of pages6
JournalChemical Physics Letters
Volume305
Issue number5-6
DOIs
Publication statusPublished - 1999 May 28

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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