Photoionization electronic spectroscopy of AlAg

D. L. Robbins; C. S. Yeh; J. S. Pilgrim; G. L. Lang; M. A. Duncan

doi:10.1063/1.466268

Photoionization electronic spectroscopy of AlAg

D. L. Robbins, C. S. Yeh, J. S. Pilgrim, G. L. Lang, M. A. Duncan

Department of Chemistry

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11 Citations (Scopus)

Abstract

AlAg is produced in a supersonic molecular beam by laser vaporization of alloy samples in a pulsed nozzle cluster source. Electronic spectroscopy is studied with resonant two-photon photoionization. In addition to the two electronic excited states previously reported by Clements and Barrow, we have observed ten new states. Vibrational analyses are presented for each of these states, and rotational analyses are given for selected states. The number and characteristics of these excited states are compared to the predictions of recent ab initio calculations.

Original language	English
Pages (from-to)	4775-4783
Number of pages	9
Journal	The Journal of Chemical Physics
Volume	100
Issue number	7
DOIs	https://doi.org/10.1063/1.466268
Publication status	Published - 1994

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Photoionization electronic spectroscopy of AlAg",

abstract = "AlAg is produced in a supersonic molecular beam by laser vaporization of alloy samples in a pulsed nozzle cluster source. Electronic spectroscopy is studied with resonant two-photon photoionization. In addition to the two electronic excited states previously reported by Clements and Barrow, we have observed ten new states. Vibrational analyses are presented for each of these states, and rotational analyses are given for selected states. The number and characteristics of these excited states are compared to the predictions of recent ab initio calculations.",

author = "Robbins, {D. L.} and Yeh, {C. S.} and Pilgrim, {J. S.} and Lang, {G. L.} and Duncan, {M. A.}",

year = "1994",

doi = "10.1063/1.466268",

language = "English",

volume = "100",

pages = "4775--4783",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

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T1 - Photoionization electronic spectroscopy of AlAg

AU - Robbins, D. L.

AU - Yeh, C. S.

AU - Pilgrim, J. S.

AU - Lang, G. L.

AU - Duncan, M. A.

PY - 1994

Y1 - 1994

N2 - AlAg is produced in a supersonic molecular beam by laser vaporization of alloy samples in a pulsed nozzle cluster source. Electronic spectroscopy is studied with resonant two-photon photoionization. In addition to the two electronic excited states previously reported by Clements and Barrow, we have observed ten new states. Vibrational analyses are presented for each of these states, and rotational analyses are given for selected states. The number and characteristics of these excited states are compared to the predictions of recent ab initio calculations.

AB - AlAg is produced in a supersonic molecular beam by laser vaporization of alloy samples in a pulsed nozzle cluster source. Electronic spectroscopy is studied with resonant two-photon photoionization. In addition to the two electronic excited states previously reported by Clements and Barrow, we have observed ten new states. Vibrational analyses are presented for each of these states, and rotational analyses are given for selected states. The number and characteristics of these excited states are compared to the predictions of recent ab initio calculations.

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SP - 4775

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JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 7

ER -

Photoionization electronic spectroscopy of AlAg

Abstract

All Science Journal Classification (ASJC) codes

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