Phyllosilicate-Derived CuNi/SiO2 Catalysts in the Selective Hydrogenation of Adipic Acid to 1,6-Hexanediol

Cheng Chieh Tu, Ya Ju Tsou, Thien Dien To, Chao Huang Chen, Jyh Fu Lee, George W. Huber, Yu Chuan Lin

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

NiOx-promoted Cu-based catalysts derived from CuNi phyllosilicates were synthesized, characterized, and tested in the selective hydrogenation of adipic acid to 1,6-hexanediol. The reduction of the CuNi phyllosilicate allows finely dispersed Cu0 and Cu+ on the surface. The reduced Cu36Ni5PS catalyst was found to have a higher turnover frequency for the selective hydrogenation of adipic acid than the reduced Cu41PS, Cu40Ni1PS, and Cu31Ni10PS catalysts. This catalyst is also effective at hydrogenation of succinic acid, glutaric acid, butyric acid, pentanoic acid, and hexanoic acid to their respective alcohols. The higher activity of the reduced Cu36Ni5PS catalyst is attributed to a higher oxidation state of Cu cations.

Original languageEnglish
Pages (from-to)17872-17881
Number of pages10
JournalACS Sustainable Chemistry and Engineering
Volume7
Issue number21
DOIs
Publication statusPublished - 2019 Jan 1

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

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