Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal-Organic Polyhedra

Teng Hao Chen, Le Wang, Jonathan V. Trueblood, Vicki H. Grassian, Seth M. Cohen

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

A new strategy was developed by using a polymer ligand, poly(isophthalic acid)(ethylene oxide), to modulate the growth of metal-organic polyhedra (MOP) crystals. This macromolecular modulator can effectively control the crystal habit of several different Cu24L24 (L = isophthalic acid derivatives) MOPs. The polymer also directed the formation of MOP structures under reaction conditions that only produce metal-organic frameworks in the absence of modulator. Moreover, the polymer also enabled the deposition of MOP crystals on glass surfaces. This macromolecular modulator strategy provides an innovative approach to control the morphology and assembly of MOP particles.

Original languageEnglish
Pages (from-to)9646-9654
Number of pages9
JournalJournal of the American Chemical Society
Volume138
Issue number30
DOIs
Publication statusPublished - 2016 Aug 3

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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