Polyoxometalate adsorbed in a metal-organic framework for electrocatalytic dopamine oxidation

Wei Huan Ho; Tsung Yi Chen; Ken Ichi Otake; Yu Chuan Chen; Yi Sen Wang; Jun Hong Li; Han Yi Chen; Chung Wei Kung

doi:10.1039/d0cc04904b

Polyoxometalate adsorbed in a metal-organic framework for electrocatalytic dopamine oxidation

Wei Huan Ho, Tsung Yi Chen, Ken Ichi Otake, Yu Chuan Chen, Yi Sen Wang, Jun Hong Li, Han Yi Chen, Chung Wei Kung

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A redox-active vanadium-based polyoxometalate, V₁₀O₂₈, was post-synthetically immobilized into a water-stable zirconium-based metal-organic framework, NU-902. The adsorbed V₁₀O₂₈in NU-902 renders charge hopping in the framework in aqueous electrolytes, and the obtained V₁₀O₂₈@NU-902 can be used as a heterogeneous electrocatalyst for electrochemical dopamine sensors.

Original language	English
Pages (from-to)	11763-11766
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	79
DOIs	https://doi.org/10.1039/d0cc04904b
Publication status	Published - 2020 Oct 11

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc04904b

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title = "Polyoxometalate adsorbed in a metal-organic framework for electrocatalytic dopamine oxidation",

abstract = "A redox-active vanadium-based polyoxometalate, V10O28, was post-synthetically immobilized into a water-stable zirconium-based metal-organic framework, NU-902. The adsorbed V10O28in NU-902 renders charge hopping in the framework in aqueous electrolytes, and the obtained V10O28@NU-902 can be used as a heterogeneous electrocatalyst for electrochemical dopamine sensors.",

author = "Ho, {Wei Huan} and Chen, {Tsung Yi} and Otake, {Ken Ichi} and Chen, {Yu Chuan} and Wang, {Yi Sen} and Li, {Jun Hong} and Chen, {Han Yi} and Kung, {Chung Wei}",

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T1 - Polyoxometalate adsorbed in a metal-organic framework for electrocatalytic dopamine oxidation

AU - Ho, Wei Huan

AU - Chen, Tsung Yi

AU - Otake, Ken Ichi

AU - Chen, Yu Chuan

AU - Wang, Yi Sen

AU - Li, Jun Hong

AU - Chen, Han Yi

AU - Kung, Chung Wei

PY - 2020/10/11

Y1 - 2020/10/11

N2 - A redox-active vanadium-based polyoxometalate, V10O28, was post-synthetically immobilized into a water-stable zirconium-based metal-organic framework, NU-902. The adsorbed V10O28in NU-902 renders charge hopping in the framework in aqueous electrolytes, and the obtained V10O28@NU-902 can be used as a heterogeneous electrocatalyst for electrochemical dopamine sensors.

AB - A redox-active vanadium-based polyoxometalate, V10O28, was post-synthetically immobilized into a water-stable zirconium-based metal-organic framework, NU-902. The adsorbed V10O28in NU-902 renders charge hopping in the framework in aqueous electrolytes, and the obtained V10O28@NU-902 can be used as a heterogeneous electrocatalyst for electrochemical dopamine sensors.

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EP - 11766

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

Polyoxometalate adsorbed in a metal-organic framework for electrocatalytic dopamine oxidation

Abstract

All Science Journal Classification (ASJC) codes

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